Structure Formation of the Chromium Carbide-Based Cermet with Copper—Nickel—Manganese Binder

L. S. Shlapak$^{1}$, Th. Shihab$^{2}$, P. M. Prysyazhnyuk$^{1}$, I. P. Yaremiy$^{3}$

$^{1}$Ivano-Frankivsk National Technical University of Oil and Gas, 15 Karpatska Str., 76019 Ivano-Frankivsk, Ukraine
$^{2}$Middle Technical University, Engineering Technical College of Baghdad, Al-Zaafranya Str., 29132 Baghdad, Iraq
$^{3}$Vasyl Stefanyk Precarpathian National University, 57 Shevchenko Str., 76018 Ivano-Frankivsk, Ukraine

Received: 05.04.2016; final version - 29.06.2016. Download: PDF

The structure of Cr$_{3}$C$_{2}$-based cermets with a binder of manganese cupronickel is studied. The cermets are fabricated by means of the infiltration of porous carbide skeletons with manganese cupronickel alloy. To obtain porous preforms, chromium carbide powder with average particle size of $\cong$ 4 $\mu$m is mixed as a 5% solution of rubber in benzene and then is briquetted under pressure of $\cong$ 500 MPa. After that process, they are sintered in vacuum at 1250°C. After such a thermal treatment, the skeletons’ open porosity is 40%. The pressureless infiltration is performed by the top-down method at 1150°C for 10 min, and the CuNiMn 60-20-20 grade manganese cupronickel is used as an infiltration alloy. The mass of infiltration material is calculated so that 100% pores in briquettes are filled. The structure of obtained cermets is studied using a ZEISS EVO 40XVP scanning electron microscope with an INCA Energy microanalysis, and the X-ray studies are performed on a DRON-3 diffractometer in the filtered CuK$_{\alpha}$-radiation. The resultant materials have three-phase composition: solid solution based on copper, Cr$_{3}$C$_{2}$ and (Cr,Mn)$_{7}$C$_{3}$, which is allocated as a disperse inclusions in binder phase and on the carbide grain boundaries; the residual porosity is within 1%. The analysis of phases’ size distribution of the Cr$_{3}$C$_{2}$ and (Cr,Mn)$_{7}$C$_{3}$ grains shows that their mean grain sizes are 5.6 $\mu$m and 1.7 $\mu$m, respectively, and the width of intergranular layers of Cu-based binder is 3.6 m. The analysis of the interaction zone shows that the width of a diffusion zone around Cr$_{3}$C$_{2}$ grains, which is formed due to the redistribution of Сr, Mn, and Cu, is about 5 $\mu$m. This fact indicates the strong bonding between the Cr$_{3}$C$_{2}$ and metal binder due to the limited solubility and new (Cr,Mn)$_{7}$C$_{3}$-phase formation. The relative wear resistance of studied cermets determined under fixed abrasive friction conditions is nearly 3 times higher than one of serial high-chromium iron-based hard-facing alloys (such as somite). Due to their high wear resistance and heterogeneous structure, the investigated cermets can be used as an alternative to tungsten hard alloys for fabricating seal faces of centrifugal pumps.

Key words: cermets, manganese cupronickel, chromium carbide, infiltration, microstructure.

URL: http://mfint.imp.kiev.ua/en/abstract/v38/i07/0969.html

DOI: https://doi.org/10.15407/mfint.38.07.0969

PACS: 81.05.Bx, 81.05.Je, 81.05.Mh, 81.05.Ni, 81.20.Ev, 81.40.Pq, 81.70.Jb

Citation: L. S. Shlapak, Th. Shihab, P. M. Prysyazhnyuk, and I. P. Yaremiy, Structure Formation of the Chromium Carbide-Based Cermet with Copper—Nickel—Manganese Binder, Metallofiz. Noveishie Tekhnol., 38, No. 7: 969—980 (2016) (in Ukrainian)


REFERENCES
  1. R. S. Dean and C. T. Anderson, Am. Soc. Metals Trans., 29: 808 (1941).
  2. B. E. Paton and D. A. Dudko, Avtomatycheskaya Svarka, 11: 44 (1966) (in Russian).
  3. L. I. Danilov and F. M. Rovenskikh, Metallurg, 29: 12 (1973).
  4. V. P. Bondarenko, Tribotekhnicheskie Kompozity s Vysokomodul'nymi Napolnitelyami (Kiev: Naukova Dumka: 1987) (in Russian).
  5. V. Ya. Belousov, Sov. Mater. Sci., 15, 29: 12 (1979).
  6. V. Ya. Belousov, Dolgovechnost' Detaley Mashin s Kompozitsionnymi Materialami (Lvov: Vyshcha Shkola: 1984) (in Russian).
  7. I. Spyrydonova and O. Sukhova, Fizyka i Khimiya Tverdoho Tila, 3, 3: 503 (2002) (in Ukrainian).
  8. E. V. Sukhovaya, Sverkhtverdye Materialy, 5: 29 (2013) (in Russian).
  9. A. D. Panasyuk, V. S. Fomenko, and G. G. Glebova, Stoykost' Nemetallicheskikh Materialov v Rasplavakh. Spravochnik (Kiev: Naukova Dumka: 1986).
  10. G. V. Samsonov and I. M. Vinnitskiy, Tugoplavkie Soedineniya. Spravochnik (Moscow: Metallurgiya: 1976) (in Russian).
  11. P. Prysyazhnyuk, D. Lutsak, A. Vasylyk, T. Shihab, and M. Burda, Metallurgical and Mining Industry, 12: 346 (2015).
  12. D. Lutsak, P. Prysyazhnyuk, and M. Karpash, Metallurgical and Mining Industry, 2: 126 (2016).