Issues »  Volume 36, Issue 11

Influence of Nonstoichiometry of a Carbide Phase of Fe—Al—C System on Its Electronic Structure and Magnetic Properties

O. A. Mekhed, V. A. Andryushchenko

G.V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03680 Kyiv-142, Ukraine

Received: 04.03.2014; final version - 29.10.2014. Download: PDF

Investigation of influence of unit cell parameters on electronic structure, magnetic moments and enthalpy of formation of carbide phase in Fe—Al—C system is carried out. Structures of Fe—C and Fe—Al bonds in Fe$_{3}$AlC$_{0.66}$ compound and their change caused by the unit cell volume change are considered on the basis of calculated electron densities of states.

Key words: electronic structure, enthalpy, $K$-phase, carbide phase, nonstoichiometry.

URL: http://mfint.imp.kiev.ua/en/abstract/v36/i11/1443.html

DOI: https://doi.org/10.15407/mfint.36.11.1443

PACS: 71.15.Ap, 71.15.Mb, 71.15.Nc, 71.20.Be, 71.55.Ak, 75.50.Bb

Citation: O. A. Mekhed and V. A. Andryushchenko, Influence of Nonstoichiometry of a Carbide Phase of Fe—Al—C System on Its Electronic Structure and Magnetic Properties, Metallofiz. Noveishie Tekhnol., 36, No. 11: 1443—1452 (2014) (in Russian)

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