Influence of Atmospheric Oxygen on Composition and Kinetic Properties of Thin Films of Bismuth
M. V. Dobrotvorska1, D. S. Orlova2, O. I. Rogachova2, O. G. Fedorov1
1Institute for Single Crystals, NAS of Ukraine, 60 Nauky Ave., 61178 Kharkiv, Ukraine
2National Technical University ‘Kharkiv Polytechnic Institute’, 21 Kyrpychov Str., 61002 Kharkiv, Ukraine
Received: 12.09.2017. Download: PDF
The effect of air oxidation on the composition and properties of bismuth films with thicknesses d = 10–200 nm is studied by using X-ray photoelectron spectroscopy and measuring electrical and galvanomagnetic properties of the films. The properties of two sets of freshly prepared films (with a protective EuS layer and without it) are compared with the properties of the same films after long-term air storage (during 9 years) at room temperature. As determined, a non-uniform in depth oxidation with the Bi2O3 formation takes place in the Bi films without protective covering. At the same time, the values of the Hall coefficient RH and magnetoresistance Δρ/ρ as well as their temperature dependences are not practically changed after air storage, whereas electrical conductivity σ is decreased. For the thinner films, the more significant decrease in σ is observed. On the other hand, after long-term air storage, in the films covered by europium sulphide, Bi is presented only in the metallic state, and σ, RH and Δρ/ρ remain practically changeless. As follows from the obtained results, in the case of presence of the protective covering, even long-term air storage at room temperature does not lead to a change either in the chemical composition or in the kinetic properties of bismuth films.
Key words: bismuth films, bismuth oxide, oxidation, electrical conductivity, Hall coefficient, magnetoresistance, X-ray photoelectron spectroscopy.
URL: http://mfint.imp.kiev.ua/en/abstract/v39/i10/1307.html
DOI: https://doi.org/10.15407/mfint.39.10.1307
PACS: 64.75.Lm, 73.50.Jt, 73.50.Lw, 73.61.At, 75.47.Np, 81.07.Bc, 81.65.Mq
Citation: M. V. Dobrotvorska, D. S. Orlova, O. I. Rogachova, and O. G. Fedorov, Influence of Atmospheric Oxygen on Composition and Kinetic Properties of Thin Films of Bismuth, Metallofiz. Noveishie Tekhnol., 39, No. 10: 1307—1319 (2017) (in Russian)