Physicochemical Fundamentals of a Self-Propagating High-Temperature Synthesis Process of Fabrication of Alloys Based on Rare-Earth Metals

Issues » Volume 39, Issue 10

A. P. Mukhachev$^{1}$, O. А. Kharytonova$^{2}$

$^{1}$Centre of Chemical Technology of AISU, 51900 Kamianske, Ukraine
$^{2}$Dniprodzerzhinsk State Technical University, 2 Dniprobudivska Str., 51918 Dneprodzerzhinsk, Ukraine

Received: 13.03.2017; final version - 10.09.2017. Download: PDF

The application fields of rare-earth metals (REM) for the fabrication of high-strength cast iron and structural steel are analysed. The physical and chemical fundamentals of industrial process and equipment are developed for the production of REM master alloys, basing on self-propagating high-temperature synthesis (SHS) process and out-of-furnace thermal reduction methods. Homogeneous multicomponent REM-alloys’ ingots for cast iron and steel alloying are fabricated.

Key words: REM alloys, reduction smelting, SHS process, fluorides, oxides, calcium, aluminium, nickel, reactor, burning rate.

URL: http://mfint.imp.kiev.ua/en/abstract/v39/i10/1395.html

DOI: https://doi.org/10.15407/mfint.39.10.1395

PACS: 64.30.Ef, 81.05.Bx, 81.10.Fq, 81.20.Ka, 82.33.Vx, 82.60.Cx, 82.60.Fa

Citation: A. P. Mukhachev and O. А. Kharytonova, Physicochemical Fundamentals of a Self-Propagating High-Temperature Synthesis Process of Fabrication of Alloys Based on Rare-Earth Metals, Metallofiz. Noveishie Tekhnol., 39, No. 10: 1395—1409 (2017) (in Russian)

REFERENCES

M. P. Braun, Mikrolegirovanie Stali (Kiev: Naukova Dumka: 1982) (in Russian).
Ya. E. Gol'zatein and V. G., Mizin, Modifitsirovanie i Mikrolegirovanie Chuguna i Stali (Moscow: Metallurgiya: 1986) (in Russian).
E. M. Savitskii, Redkie Metally i Splavy (Moscow: Dom Tekhniki: 1959) (in Russian).
A. Prochovnick, Literature Search Relating to Metallurgical Applications of the Rare Earths (Pompton Plains: Davison Chemical Company: 1958), No. 1.
V. M. Azhazha, B. V. Borts, A. F. Vanzha, N. D. Rybal'chenko, and E. P. Shevyakova, Voprosy Atomnoy Nauki i Tekhniki, No. 1: 195 (2008) (in Russian).
E. M. Savitskii, V. F. Terekhova, I. V. Burov, I. A. Markova, and O. P. Naumkin, Splavy Redkozemel'nykh Elementov (Moscow: Izd-vo AN USSR: 1962) (in Russian).
K. A. Gschneidner, Jr., Splavy Redkozemel'nykh Elementov [Rare Earth Alloys] (Moscow: Mir: 1965) (Russian translation).
Redkozemel'nye Metally [The Rare Earths] (Eds. F. H. Spedding and A. H. Daane) (Moscow: Metallurgiya: 1965) (Russian translation).
N. P. Sokolov and L. I. Kachur, Kaltsiytermicheskoe Vosstanovlenie Ftoridov Redkozemelnykh Metallov (Moscow: Tsvetnye Metally: 1994) (in Russian).
Alyumotermiya (Ed. N. P. Lyakishev) (Moscow: Metallurgiya: 1978) (in Russian).
N. N. Murach and U. D. Veretin, Vnepechnaya Metallotermiya (Moscow: Metallurgiya: 1956) (in Russian).
V. A. Podergin and G. V. Samsonov, Izv. AN USSR. Metallurgiya i Gornoe Delo, No. 5: 50 (1963) (in Russian).
E. L. Levashov, A. S. Rogachev, V. V. Kurbatkina, Yu. M. Maksimov, and V. I. Yukhvid, Perspektivnye Materialy i Tehnologii Samorasprostranyayushchegosya Vysokotemperaturnogo Sinteza: Uchebnoe Posobie (Moscow: Izd. Dom MISiS: 2011) (in Russian).
O. Kubaschewski and C. B. Alcock, Metallurgicheskaya Termokhimiya [Metallurgical Thermochemistry] (Moscow: Metallurgiya: 1982) (Russian translation).
V. A. Kireev, Metody Prakticheskikh Raschetov v Termodinamike Khimicheskikh Reaktsiy (Moscow: Khimiya 1970) (in Russian).
N. P. Galkin, Termodinamicheskie Svoystva Neorganicheskikh Ftoridov (Moscow: Atomizdat: 1972) (in Russian).
C. E. Wicks and F. E. Block, Termodinamicheskie Svoystva 65 Elementov, Ikh Oksidov, Galogenidov, Karbidov i Nitridov [Thermodynamic Properties of 65 Elements—Their Oxides, Halides, Carbides, and Nitrides] (Moscow: Metallurgiya: 1965) (Russian translation).
V. L. Safronov, Tezisy Dokladov 'Vsesoyuznogo Simpoziuma po Khimii Neorganicheskikh Ftoridov' (June 27–30, 1978) (Dnepropetrovsk: Nauka: 1978), p. 264 (in Russian).