Hydrogen Treatment of Silicon Surface Following Proton Irradiation

А. Vasiljev$^{1}$, T. Vasyliev$^{1}$, А. Vdovenkov$^{1}$, O. Kukharenko$^{1,2}$, T. Doroshenko$^{3}$, M. Tolmachov$^{2}$

$^{1}$Taras Shevchenko National University of Kyiv, 60 Volodymyrska Str., UA-01033 Kyiv, Ukraine
$^{2}$Cooperation Center ‘Kyiv Scanning Ion Microprobe’ of Taras Shevchenko National University of Kyiv and Company ‘T.M.M.’ Limited, 50A Mashynobudivna Str., UA-03067 Kyiv, Ukraine
$^{3}$V. E. Lashkaryov Institute of Semiconductor Physics, NAS of Ukraine, 41 Nauky Ave., UA-03028 Kyiv, Ukraine

Received: 28.02.2020; final version - 18.08.2020. Download: PDF

The present work demonstrates that hydrogen treatment is capable to destroy and to split the surface of silicon single crystal. Hydrogen treatment is performed after the proton irradiation of the silicon surface. All operations with the silicon single crystal are performed at room temperature. The surface of the crystal is irradiated with a proton beam. The proton energy in the beam is 1.5 MeV. The energy spread did not exceed 150 eV. The integral radiation fluence is 2$\cdot10^{14}$ p/cm$^2$. Such a dose of radiation is sufficient to form a thin layer with a high density of radiation defects at a depth of 30 $\mu$m under the surface. The existence of this thin layer is confirmed after chemical manifestation by observations on the electron microscope. After irradiation, an electrolytic saturation of the silicon sample with hydrogen is carried out through the irradiated surface. During electrolysis, the irradiated surface of the sample uses as a cathode and the graphite electrode—as an anode. The solution of 10% H$_2$SO$_4$ and 2% KF in water is used for electrolysis. The electrolytic current density is 57.15 mA/cm$^2$. After 10 minutes of electrolytic saturation of the sample with hydrogen, part of the sample is split. A portion of the irradiated sample is split along the layer with a high density of radiation defects.

Key words: proton irradiation, radiation defects, hydrogen treatment, nanoporous silicon surface.

URL: http://mfint.imp.kiev.ua/en/abstract/v42/i10/1325.html

DOI: https://doi.org/10.15407/mfint.42.10.1325

PACS: 61.72.uf, 68.35.bj, 81.40.Np, 81.40.Wx, 81.65.-b

Citation: А. Vasiljev, T. Vasyliev, А. Vdovenkov, O. Kukharenko, T. Doroshenko, and M. Tolmachov, Hydrogen Treatment of Silicon Surface Following Proton Irradiation, Metallofiz. Noveishie Tekhnol., 42, No. 10: 1325—1334 (2020)


REFERENCES
  1. V. A. Goltsov, A. G. Vasiljev, N. N. Vlasenko, and D. Fruchart, Int. J. Hydrogen Energy, 27, Iss. 7-8: 765 (2002). Crossref
  2. A. G. Vasiljev, N. N. Vlasenko, V. A. Goltsov, and D. Fruchart, Metallofiz. Noveishie Tekhnol., 21, No. 11: 87 (1999) (in Russian).
  3. A. G. Vasiljev, Metallofiz. Noveishie Tekhnol., 33, No. 10: 765 (2011) (in Russian).
  4. A. G. Vasiljev, O. I. Kozonushchenko, T. A. Vasyliev, V. V. Zhuravel, and T. P. Doroshenko, J. Nano- and Electronic Physics, 11, No. 3: 03003 (2019). Crossref
  5. V. V. Kozlovskii, V. A. Kozlov, and V. N. Lomasov, Semiconductors, 34: 123 (2000). Crossref
  6. H. Foll, J. Carstensen, and S. Frey, Journal of Nanomaterials, 2006, No. 1: 91635 (2006). Crossref
  7. Ş. Doğan, N. Akın, C. Başköse, T. Asar, T. Memmedli, and S. Özçelik, J. Mater. Sci. Eng. B, 3, No. 8: 518 (2013). Crossref
  8. W. Li, Z. Liu, F. Fontana, Y. Ding, D. Liu, J. T. Hirvonen, and H. A. Santos, Adv. Mater., 30, 24: 1703740 (2018). Crossref
  9. S. A. Lebed, O. G. Kukharenko, N. G. Tolmachov, and O. V. Tretiak, Voprosy Atomnoy Nauki i Tekhniki, No. 5(81): 131 (2012) (in Ukrainian).
  10. J. F. Ziegler, J. P. Biersack, and U. Liimark, Treatise on Heavy-Ion Science, 1: 93 (Boston: Springer: 1985). Crossref
  11. G. Alefeld and J. Völkl, Hydrogen in Metals II. Series Topics in Applied Physics (Berlin: Springer-Verlag: 1978). Crossref
  12. J. H. Park, Q. Wang, K. Zhu, A. J. Frank, and J. Y. Kim, ACS Publications, 4, No. 22: 19772 (2019). Crossref
  13. S. H. Lee, J. S. Kang, and D. Kim, Materials, 11, No. 12: 2557 (2018). Crossref