Magnetic Properties of Cu/Cu2O Nanoparticles of ‘Nucleus–Shell’ Class Prepared by Electric-Spark Dispergation Method
А. О. Perеkоs1, О. D. Rud1, V. Z. Vоynash1, А. V. Gіlchuk2, М. О. Gоlyatkinа2, V. V. Bоndаr1, S. М. Kоnоplyuk3, V. М. Kоlyesnik1, Ye. Yu. Kanyukоv4, М. А. Kаlаndа4, S. Ye. Demyanov4
1G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine
2National Technical University of Ukraine ‘Igor Sikorsky Kyiv Polytechnic Institute’, 37 Peremohy Ave., UA-03056 Kyiv, Ukraine
3Institute of Magnetism under NAS and MES of Ukraine, 36b Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine
4Scientific and Practical Materials Research Centre of NAS of Belarus, 19 P. Brovki Str., 220072 Minsk, Republic of Belarus
Received: 15.01.2020; final version - 12.06.2020. Download: PDF
The spherical Cu/Cu2O nanoparticles of ‘nucleus–shell’ class with submicron sizes are fabricated by method of electrospark dispergation in distilled water. As shown, the produced nanoparticles at room temperature have ferromagnetic properties and values of its specific magnetization saturation are in interval from 0.1 to 3 G⋅cm3/g. As assumed, ferromagnetic properties of Cu/Cu2O nanoparticles’ ensembles are connected with localized magnetic moments formation on interfaces between nucleuses of nanoparticles and their shells. Interaction of these localized magnetic moments and formation of total magnetic moments of separate nanoparticles with their following blocking by magnetic dipole-dipole interaction or by field of their magnetic anisotropy may leads to correlated orientation of nanoparticles’ magnetic moments and to creation of ferromagnetic state.
Key words: magnetic properties, electric-spark dispergation, nanoparticles of ‘nucleus–shell’ class, ferromagnetism.
URL: http://mfint.imp.kiev.ua/en/abstract/v42/i11/1481.html
DOI: https://doi.org/10.15407/mfint.42.11.1481
PACS: 61.05.cp, 61.43.Gt, 61.46.Hk, 75.20.-g, 75.50.Cc, 75.75.-c
Citation: А. О. Perеkоs, О. D. Rud, V. Z. Vоynash, А. V. Gіlchuk, М. О. Gоlyatkinа, V. V. Bоndаr, S. М. Kоnоplyuk, V. М. Kоlyesnik, Ye. Yu. Kanyukоv, М. А. Kаlаndа, and S. Ye. Demyanov, Magnetic Properties of Cu/Cu2O Nanoparticles of ‘Nucleus–Shell’ Class Prepared by Electric-Spark Dispergation Method, Metallofiz. Noveishie Tekhnol., 42, No. 11: 1481—1497 (2020) (in Ukrainian)