Hydrogen Absorption and Desorption by Niobium and Tantalum
V. A. Dekhtyarenko, D. G. Savvakin, O. O. Stasiuk, D. V. Oryshych
G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine
Received: 25.05.2022; final version - 13.06.2022. Download: PDF
Studies are shown that tantalum and niobium have different kinetics of hydrogen uptake. Tantalum, in contrast to niobium, is able absorb actively hydrogen at room temperature, reaching a hydrogen capacity at the level of TaN$_{1.9}$. Active absorption of hydrogen by niobium is observed only at heating to temperatures of 400–500°C, reaching the hydrogen capacity of NbH$_{1.23}$. The kinetics of hydrogen evolution from both hydrogen-saturated metals is similar, the process takes place at room temperature, but in different pressure conditions.
Key words: niobium, tantalum, hydrogenation, dehydrogenation, powder.
URL: https://mfint.imp.kiev.ua/en/abstract/v44/i07/0887.html
DOI: https://doi.org/10.15407/mfint.44.07.0887
PACS: 61.66.Dk, 61.72.Yx, 64.75.-g, 68.43.Mn, 82.30.Rs, 82.80.-d
Citation: V. A. Dekhtyarenko, D. G. Savvakin, O. O. Stasiuk, and D. V. Oryshych, Hydrogen Absorption and Desorption by Niobium and Tantalum, Metallofiz. Noveishie Tekhnol., 44, No. 7: 887—897 (2022)