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Effects of ‘Orbital Glass’. 5. Spin–Orbit Coupling in Metals

O. I. Mitsek, V. M. Pushkar

G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine

Received: 30.05.2024; final version - 06.06.2024. Download: PDF

Spin–orbit coupling in groups of (3d, 4f, 5f) ions by means of the segregation of their orbital moments Lr creates new substance—orbital glass. In many-electron operator-spinors’ representation, spin–orbit coupling in sea of band fermions (fr or hr) is expressed by their density (ne of electrons or nh of holes). The orbital-glass influence on bond spectra εk(e,h) is expressed by segregation-excitation energies. Fractional spin (S) and orbital (L) moments of 3d-elements are determined by spin–orbit coupling. Light 4f-elements have orbital moment L < 0 due to electron charges er < 0, but heavy elements have orbital moment L > 0 due to hole charges hr > 0.

Key words: spin–orbit coupling, orbital glass.

URL: https://mfint.imp.kiev.ua/en/abstract/v46/i07/0615.html

DOI: https://doi.org/10.15407/mfint.46.07.0615

PACS: 71.10.Fd, 71.70.Ej, 75.10.Dg, 75.30.Et, 75.50.Lk, 75.60.Ch, 75.70.Tj

Citation: O. I. Mitsek and V. M. Pushkar, Effects of ‘Orbital Glass’. 5. Spin–Orbit Coupling in Metals, Metallofiz. Noveishie Tekhnol., 46, No. 7: 615—620 (2024) (in Ukrainian)


REFERENCES
  1. S. V. Vonsovsky, Magnetizm [Magnetism] (Moskva: Nauka: 1971) (in Russian).
  2. A. A. Smirnov, Teoriya Splavov Vnedreniya [Theory of Interstitial Alloys] (Moskva: Nauka: 1979) (in Russian).
  3. O. I. Mitsek and V. M. Pushkar, Metallofiz. Noveishie Tekhnol., 42, No. 9: 1315 (2020) (in Ukrainian). Crossref
  4. A. V. Deryagin and A. V. Andreev, ZhETF, 71, No. 9: 1166 (1976) (in Russian).
  5. G. E. R. Schulze, Metallofizika [Metal Physics] (Moskva: Mir: 1971) (Russian translation).
  6. N. Chebotarev, Osnovy Teorii Galua [Basics of Galois Theory] (Moskva: Gosudarstvennoye Tekhniko-Teoreticheskoye Izdatel'stvo: 1934) (in Russian).