An Improvement of Liquid-Phase Methods for Growing of the Mo and W Single Crystals
V. Shapovalov, V. Yakusha, Y. Nikitenko, I. Protokovilov, J. Khokhlova, O. Hnizdylo
E. O. Paton Electric Welding Institute, NAS of Ukraine, 11 Kazymyr Malevych Str., UA-03150 Kyiv, Ukraine
Received: 01.10.2024; final version - 02.10.2024. Download: PDF
Single crystals of refractory metals with a given orientation are demanded in both the power-optics and high-power laser applications. The evolution of liquid-phase methods for growing such refractory metals as the molybdenum and tungsten single crystals is analysed. As shown, the methods for growing crystals with a single heating source cannot solve the problem of fabrication of industrial-sizes’ crystals. The superlarge single crystals of various configurations, such as ingot and plates, can be grown using the combined plasma-induction method. The single-crystalline quality of the ingots and the preservation of the orientations of the selected crystallographic axes are confirmed by the x-ray method according to Laue images. The repeatability of physical and mechanical properties is shown by the indentation test.
Key words: tungsten, molybdenum, single crystal, plasma-induction zone melting.
URL: https://mfint.imp.kiev.ua/en/abstract/v46/i10/0953.html
DOI: https://doi.org/10.15407/mfint.46.10.0953
PACS: 06.60.Vz, 61.72.Lk, 61.72.Mm, 64.70.dg, 81.10.Fq, 81.20.Hy, 81.70.Bt
Citation: V. Shapovalov, V. Yakusha, Y. Nikitenko, I. Protokovilov, J. Khokhlova, and O. Hnizdylo, An Improvement of Liquid-Phase Methods for Growing of the Mo and W Single Crystals, Metallofiz. Noveishie Tekhnol., 46, No. 10: 953—962 (2024)