Structural Studies of Silver Nanoparticles in Hydrogel Composites

O. S. Sukhanevych$^{1}$, I. V. Olkhovyk$^{1}$, A. V. Kotko$^{3}$, M. V. Iurzhenko$^{2}$, V. L. Demchenko$^{2}$, D. V. Kunytskyi$^{2}$, V. B. Neimash$^{4}$, G. E. Monastyrskyi$^{1}$

$^{1}$Institute of Physics and Technology, Igor Sikorsky Kyiv Polytechnic Institute, 37 Beresteys’kyy Ave., UA-03056 Kyiv, Ukraine
$^{2}$E. O. Paton Electric Welding Institute of the N.A.S. of Ukraine, 11 Kazimir Malevich Str., UA-03150 Kyiv, Ukraine
$^{3}$I. M. Frantsevych Institute for Materials Science of the N.A.S. of Ukraine, 3 Omeljan Pritsak Str., UA-03142 Kyiv, Ukraine
$^{4}$Institute of Physics of the NAS of Ukraine, 46 Nauky Ave., UA-03028 Kyiv, Ukraine

Received: 18.03.2025; final version - 15.10.2025. Download: PDF

The article is concerned with the study of the structure of silver nanoparticles formed in a hydrogel as a result of irradiation of a solution of silver nitrate in a mixture of polyvinyl alcohol and polyethylene glycol by high-energy electrons. The reduction of Ag nitrate to metallic silver as a result of irradiation is confirmed by x-ray diffraction analysis. The dynamic light-scattering method confirms that, in irradiated liquid solutions of AgNO3, the nanoparticles’ size distribution is bimodal. The presence of predominantly spherical silver nanoparticles and Ag2O ones is revealed by transmission electron-microscopy method.

Key words: silver nanoparticles, hydrogel, high-energy electron irradiation.

URL: https://mfint.imp.kiev.ua/en/abstract/v47/i12/1257.html

DOI: https://doi.org/10.15407/mfint.47.12.1257

PACS: 61.05.cp, 61.46.Df, 61.80.Fe, 68.37.Lp, 81.07.Pr, 81.40.Wx, 87.85.Rs

Citation: O. S. Sukhanevych, I. V. Olkhovyk, A. V. Kotko, M. V. Iurzhenko, V. L. Demchenko, D. V. Kunytskyi, V. B. Neimash, and G. E. Monastyrskyi, Structural Studies of Silver Nanoparticles in Hydrogel Composites, Metallofiz. Noveishie Tekhnol., 47, No. 12: 1257–1268 (2025) (in Ukrainian)


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