Application of the Process of Self-Propagating High-Temperature Synthesis for the Fabrication of Modifying Composite Ceramic–Metal Powders

S. O. Luzan

National Technical University ‘Kharkiv Polytechnic Institute’, 2 Kyrpychova Str., UA-61002 Kharkiv, Ukraine

Received: 14.07.2025; final version - 10.03.2026. Download: PDF

The processes based on self-propagating high-temperature synthesis (SHS) for the fabrication of two types of modifying composite materials (MCM) of a charge containing boron: Ti, B, C, Fe2O3, Al, PT-NA-01, and a charge, in which silicon (SiO2) and aluminium (Al2O3) oxides in the form of refractory clay of the PGOSA-0 brand are included instead of expensive boron (B). The thermodynamic evaluation of the possibility of interplay between the components is carried out using the Gibbs energy. The phase compositions of the deposited coatings with composite materials (CM) based on PG-10N-01 alloy and their microhardness are presented. The results of studies of the wear resistance of CM during the friction against fixed abrasive particles show 1.5-2.4 times higher wear resistance compared to the PG-10N-01 alloy. As established, the deposited CM modified by the MCM, which contains silicon (SiO2) and aluminium (Al2O3) oxides instead of boron (B), has higher wear resistance, when it works in an abrasive environment. This is due to the content of chromium, titanium, silicon, and boron carbides in its structure. The morphology of the friction surfaces is also in a good agreement with the results of friction tests upon fixed particles of the deposited coatings PG-10N-01 and СM.

Key words: composite material, boride, SHS process, surfacing, wear resistance.

URL: https://mfint.imp.kiev.ua/en/abstract/v48/i07/0703.html

DOI: https://doi.org/10.15407/mfint.48.07.0703

PACS: 62.20.Qp, 68.55.J-, 81.05.Je, 81.20.Ev, 81.20.Ka, 81.40.Pq, 82.33.Vx

Citation: S. O. Luzan, Application of the Process of Self-Propagating High-Temperature Synthesis for the Fabrication of Modifying Composite Ceramic–Metal Powders, Metallofiz. Noveishie Tekhnol., 48, No. 7: 703–714 (2026)


REFERENCES
  1. M. Yu. Osipov, Innovative Materials and Technologies in Metallurgy and Mechanical Engineering, 1: 52 (2014).
  2. S. O. Luzan, V. A. Bantkovskiy, and A. S. Luzan, Metallofiz. Noveishie Tekhnol., 44, No. 4: 531 (2022).
  3. R. M. German, Powder Metallurgy and Particulate Materials Processing (Princeton, USA: Metal Powder Industries Federation: 2005).
  4. A. Makino, Prog. Energy Combust. Sci., 27: 1 (2001).
  5. S. O. Luzan and P. A. Sytnykov, Herald of Khmelnytskyi National University. Technical Sciences, 323, No. 4: 194 (2023).
  6. S. O. Lusan and P. A. Sytnykov, Funct. Mater., 30, No. 4: 526 (2023).
  7. V. I. Savuliak, Syntez Znosostiykykh Kompozytsiynykh Materialiv ta Poverkhnevykh Shariv z Ehkzotermichnykh Komponentiv [Synthesis of Wear-resistant Composite Materials and Surface Layers of Exothermic Components] (Vinnytsia: UNIVERSUM-Vinnytsia: 2002) (in Ukrainian).
  8. S. O. Luzan and P. A. Sytnykov, Visnyk Kremenchutskoho Natsionalnoho Universytetu im. Mykhaila Ostrohradskoho, 4: 88 (2022) (in Ukrainian).
  9. B. Trembach, Y. Silchenko, O. Balenko, D. Hlachev, K. Kulahin, H. Heiko, O. Bellorin-Herrera, S. Khabosha, O. Zakovorotnyi, and I. Trembach, Int. J. Adv. Manuf. Technol., 134: 309 (2024).
  10. B. O. Trembach, Yu. A. Silchenko, M. G. Sukov, N. B. Ratska, Z. A. Duriagina, I. V. Krasnoshapka, O. V. Kabatskyi, and O. M. Rebrova, Mater. Sci., 59: 733 (2024).
  11. A. Chrysanthou, Adv. in Sci. and Techn., 63: 273 (2010).
  12. E. G. Dyadko, Samorasprostranyayushchiysya Vysokotemperaturnyi Sintez Kompozitsionnykh Materialov na Osnove Karbida Titana i Oksida Alyuminiya dlya Abrazivnoy i Magnitno-Abrazivnoy Obrabotki (Self-Propagating High-Temperature Synthesis of Composite Materials Based on Titanium Carbide and Aluminum Oxide for Abrasive and Magnetic-Abrasive Machining) (Ph.D. Thesis Abstract) (Kiev: Frantsevich Institute for Problems in Materials Science: 1988) (in Russian).
  13. S. A. Luzan, A. Y. Sydashenko, and A. S. Luzan, Tekhnichnyi Servis Ahropromyslovoho, Lisovoho ta Transportnoho Kompleksiv, 6: 152 (2016) (in Ukrainian).