Influence of Technological Parameters of Deposition on Physical and Mechanical Properties of Vacuum-Arc Multilayer Nitride Coatings Based on Chromium and Niobium

I. V. Serdiuk$^{1}$, S. I. Petrushenko$^{2,3}$, V. O. Stolbovyi$^{1}$, M. Fijalkowski$^{3}$

$^{1}$Национальный научный центр «Харьковский физико-технический институт» НАН Украины, ул. Академическая, 1, 61108 Харьков, Украина
$^{2}$Харьковский национальный университет имени В. Н. Каразина, пл. Свободы, 4, 61022 Харьков, Украина
$^{3}$Либерецкий технический университет, ул. Студенческая 1402/2, 46117 Либерец 1, Чешская Республика

Получена: 17.10.2023; окончательный вариант - 20.11.2023. Скачать: PDF

Establishing the regularities of the structure and phase formation of vacuum-arc multilayer nitride coatings at different technological parameters is important for the predicted obtaining of the required properties of multilayer systems. To analyse the influence on the physical and mechanical properties, the following technological parameters of deposition vacuum-arc multilayer nitride coatings are chosen: pressure of the reaction gas in the vacuum chamber (0.08–0.27 Pa), constant negative voltage on the substrate (70–200 V), layer thickness (17–150 nm) and number of layers (68, 270, 1080). Chromium and niobium nitrides, which are promising materials in many fields of application, are chosen as components of vacuum-arc coatings. The research show that vacuum-arc multilayer nitride coatings СrN/NbN obtained under different technological conditions have high planarity of layers and practically no drop phase in the volume of the coating. The analysis of heterogeneity of the structural and phase state of the coatings is carried out by the root-mean-square deviation of the vacuum-arc coating microhardness. The trends in changes in physical and mechanical properties are evaluated based on the average values of microhardness, contact modulus of elasticity, and others ratios.

Ключевые слова: vacuum-arc coatings, multilayer coatings, microhardness, surface morphology, physical and mechanical properties.

URL: https://mfint.imp.kiev.ua/ru/abstract/v46/i01/0023.html

PACS: 62.20.Qp, 62.23.Kn, 68.37.Hk, 68.60.-p, 68.65.Ac, 81.15.-z, 81.65.Lp


ЦИТИРОВАННАЯ ЛИТЕРАТУРА
  1. O. V. Sobol’, A. A. Andreev, V. F. Gorban’, N. A. Krapivka, V. A. Stolbovoi, I. V. Serdyuk, and V. E. Fil’chikov, Tech. Phys. Lett., 38, No. 7: 616 (2012). Crossref
  2. V. F. Gorban’, R. A. Shaginyan, N. A. Krapivka, S. A. Firstov, N. I. Danilenko, and I. V. Serdyuk, Powder Metall. Met. Ceram., 54, Nos. 11–12: 725 (2016). Crossref
  3. M. El Garah, L. Patout, A. Boussil, A. Charai, and F. Sanchette, Coatings, 13, No. 8: 1380 (2023). Crossref
  4. O. V. Sobol’, V. M. Beresnev, I. V. Serdyuk, A. D. Pogrebnyak, D. A. Kolesnikov, U. S. Nemchenko, and S. N. Grigoriev, J. Friction and Wear, 35, No. 5: 359 (2014). Crossref
  5. V. F. Horban, I. V. Serdiuk, O. M. Chuhai, O. O. Voloshin, S. V. Oliinyk, H. H. Veselivska, M. I. Danylenko, D. V. Sliusar, V. A. Stolbovyi, and O. S. Kalahan, Mat. Sci., 57, No. 3: 428 (2021). Crossref
  6. O. V. Sobol’, A. A. Andreev, V. F. Gorban, A. A. Meylekhov, A. A. Postelnyk, and V. A. Stolbovoy, J. Nano- Electron. Phys., 8, No. 1: 01042 (2016).
  7. V. O. Stolboviy, J. Nano- Electron. Phys., 9, No. 5: 05038 (2016). Crossref
  8. O. V. Sobol’, A. A. Postelnyk, A. A. Meylekhov, A. A. Andreev, V. A. Stolbovoy, and V. F. Gorban, J. Nano- Electron. Phys., 9, No. 3: 03003 (2017).
  9. A. Gilewiczn and B. Warcholinski, Tribology Int., 80: 34 (2014). Crossref
  10. J. J. Roa, E. Jiménez-Piqué, R. Martínez, G. Ramírez, J. M. Tarragó, R. Rodríguez, and L. Llanes, Thin Solid Films, 571: 308 (2014). Crossref
  11. R. A. Koshy, M. E. Graham, and L. D. Marks, Surf. Coat. Technol., 202: 1123 (2007). Crossref
  12. H. C. Barshilia, A. Jain, and K. S. Rajam, Vacuum, 72, No. 3: 241 (2004). Crossref
  13. Z. Zhang, Z. Chen, D. Holec, C. H. Liebscher, N. Koutna, M. Bartosik, Y. Zheng, G. Dehm, and P. H. Mayrhofer, Acta Mater., 194: 343 (2020). Crossref
  14. R. Mundotia, T. Ghorude, D. C. Kothari, A. Kale, and N. Thorat, Appl. Surf. Sci. Adv., 7: 100205 (2022). Crossref
  15. M. Nordin, M. Larsson, and S. Hogmark, Wear, 232, No. 2: 221 (1999). Crossref
  16. Li DeJun, Zang JingJing, and Wang MingXia, Sci. China Series E: Technol. Sci., 50: 206 (2007). Crossref
  17. Keng-Liang Ou, Microelect. Eng., 83, No. 2: 312 (2006). Crossref
  18. P. Lazar, J. Redinger, and R. Podloucky, Phys. Rev. B, 76: 174112 (2007). Crossref
  19. H. O. Postelnyk, O. V. Sobol’, V. A. Stolbovoy, I. V. Serdiuk, and O. Chocholaty, PAST, 2: 139 (2020). Crossref
  20. H. Wang, H. Zeng, Q. Li, and J. Shen, Thin Solid Films, 607: 59e66 (2016). Crossref
  21. J. Lin, J. J. Moore, B. Mishra, M. Pinkas, X. Zhang, and W. D. Sproul, Thin Solid Films, 517: 5798e5804 (2009). Crossref
  22. N. Koutna, D. Holec, M. Friak, P. H. Mayrhofer, and M. Sob, Mater. Des., 144: 310e322 (2018). Crossref
  23. J. Buchinger, N. Koutna, Z. Chen, Z. Zhang, P. H. Mayrhofer, D. Holec, and M. Bartosik, Acta Mater., 172: 18 (2019). Crossref
  24. O. V. Sobol’, A. A. Andreev, V. A. Stolbovoy, N. V. Pinchuk, and A. A. Meylekhov, J. Nano- Electron. Phys., 7, No. 1: 01026 (2015).
  25. S. A. Barnett, A. Madan, I. Kom, and K. Martin, MRS Bull., 28: 169 (2003). Crossref
  26. V. P. Rudenko, V. O. Stolbovoy, I. V. Serdiuk, and K. G. Kartmazov, East.-Eur. J. Enterp. Tech., 48, No. 6/1: 66 (2010).
  27. A. A. Andreev, L. P. Sablev, and S. N. Grigoriev, Vakuumno-Dugovyye Pokrytiya [Vacuum Arc Coatings] (Kharkov: 2010) (in Russian).
  28. Svoistva Ehlementov. Fizicheskie Svoistva [Element Properties. Physical Properties] (Ed. G. V. Samsonov) (Moskva: Metallurgy: 1976) (in Russian).
  29. G. V. Samsonov and I. M. Vinitskiy, Tugoplavkie Soedineniya [Refractory Compounds] (Moskva: Metallurgy: 1976) (in Russian).
  30. G. V. Samsonov and A. P. Epik, Tugoplavkie Pokrytiya [Refractory Coatings] (Moskva: Metallurgy: 1973) (in Russian).
  31. G. V. Samsonov, Nitridy [Nitrides] (Kievv: Naukova Dumka: 1973) (in Russian).
  32. A. G. Guglya and I. M. Neklyudov, Usp. Fiz. Met., 6, No. 3: 197 (2005). Crossref
  33. B. Warcholinski, A. Gilewicz, A. S. Kuprin, G. N. Tolmachova, V. D. Ovcharenko, T. A. Kuznetsova, V. A. Lapitskaya, and S. A. Chizhik, J. Friction Wear, 40, No. 2: 163 (2019). Crossref
  34. J. J. Olaya, L. Huerta, S. E. Rodil, and R. Escamilla, Thin Solid Films, 516: 8768 (2008). Crossref