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Phase Composition of Electrodeposited Fe—Zn Alloys

Ie. V. Kolesnyk

SHEI ‘Ukrainian State University of Chemical Technology’, 8 Gagarin Ave., 49005 Dnipropetrovs’k, Ukraine

Received: 02.10.2014; final version - 29.10.2014. Download: PDF

Presence of α-phase, Fe75Zn25, Fe3Zn10 and η-phase in electrodeposited Fe—Zn alloys is determined by the method of X-ray diffractometry. The phase proportion varies with the increase of zinc concentration in the sulphate electrolyte. Discovered formation of Fe75Zn25 phase during co-deposition of iron and zinc can be the cause of creation of previously revealed irregular surface relief with anomalously high roughness. Revision of Fe75Zn25 phase atomic composition is accomplished by the numerical method based on precise value of the crystal-lattice spacing and taking into account elastic strain caused by zinc atoms, which are dissolved in the α-Fe crystal lattice.

Key words: Fe—Zn alloys, phase composition, electrodeposited alloys, coatins.

URL: http://mfint.imp.kiev.ua/en/abstract/v37/i02/0257.html

DOI: https://doi.org/10.15407/mfint.37.02.0257

PACS: 61.05.cp, 61.66.Dk, 68.55.J-, 68.55.Nq, 81.05.Bx, 81.15.Pq, 82.45.Qr

Citation: Ie. V. Kolesnyk, Phase Composition of Electrodeposited Fe—Zn Alloys, Metallofiz. Noveishie Tekhnol., 37, No. 2: 257—264 (2015)


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