Hydrogen-Sorption Properties of a Composite (Ti—Zr—Mn—V)—Mg

V. A. Dekhtyarenko

G.V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03680 Kyiv-142, Ukraine

Received: 20.05.2015; final version - 19.09.2015. Download: PDF

The hydrogen-sorption properties of the composite consisted of Ti$_{47.5}$Zr$_{30}$Mn$_{17.5}$V$_{5}$ ingot and Mg powder is investigated. As found, the presence of magnesium powder does not affect the hydrogen sorption—desorption kinetics of bulk heterophase Ti$_{47.5}$Zr$_{30}$Mn$_{17.5}$V$_{5}$ alloy. As shown, the bulk Ti$_{47.5}$Zr$_{30}$Mn$_{17.5}$V$_{5}$ alloy is crushed into hydrides’ powder upon hydrogen sorption. The presence of the obtained hydrides’ powder led to partial hydrogenation of magnesium powder at a temperature of 340—420°C and a hydrogen pressure of 0.018 MPa.

Key words: magnesium powder, heterophase alloy, hydrogenation, dehydrogenation, hydrogen capacity.

URL: http://mfint.imp.kiev.ua/en/abstract/v38/i02/0167.html

DOI: https://doi.org/10.15407/mfint.38.02.0167

PACS: 61.05.cp, 61.66.Dk, 68.43.Mn, 68.43.Nr, 81.20.-n, 84.60.Ve, 88.30.rd

Citation: V. A. Dekhtyarenko, Hydrogen-Sorption Properties of a Composite (Ti—Zr—Mn—V)—Mg, Metallofiz. Noveishie Tekhnol., 38, No. 2: 167—174 (2016) (in Russian)


REFERENCES
  1. V. A. Legasov, N. N. Ponomarev-Stepnoy, and A. N. Protsenko, Atomno-Vodorodnaya Energetika i Tekhnologiya, 1: 11 (1978) (in Russian)
  2. I. V. Berezin, S. D. Varfolomeev, and P. P. Titov, Atomno-Vodorodnaya Energetika i Tekhnologiya, 2: 48 (1979) (in Russian)
  3. M. M. Antonova, A. B. Sapozhnikova, V. V. Skorokhod, D. M. Karpinos, L. R. Vishnyakov, and I. M. Shalya, Poroshkovaya Metallurgiya, No. 6: 63 (1986) (in Russian)
  4. M. M. Antonova, A. B. Sapozhnikova, V. V. Skorokhod, D. M. Karpinos, L. L. Rokhlin, V. N. Verbetsky, L. R. Vishnyakov, N. I. Nikitina, S. N. Klyamkin, and I. M. Shalya, Poroshkovaya Metallurgiya, No. 5: 61 (1987) (in Russian)
  5. K. N. Semenenko, V. N. Verbetskiy, A. V. Kochukov, and A. N. Sitnikov, Vestnik MGU. Ser. 2. Khimiya, 24, No. 1: 16 (1983) (in Russian)
  6. O. D. Rud', A. M. Lakhnik, V. G. Ivanchenko, V. M. Uvarov, A. A. Shkola, V. A. Dekhtyarenko, V. P. Melnichenko, L. I. Ivashchuk, and N. I. Kuskova, Metallofiz. Noveishie Tekhnol., 29, No. 11: 1467 (2007) (in Russian)
  7. V. N. Verbetskiy and S. V. Mitrokhin, Materialovedenie, 1: 48 (2009) (in Russian)
  8. V. N. Verbetskiy, Sintez i Svoystva Mnogokomponentnykh Gidridov Metallov (Thesis of Disser. for … Dr. Chem. Sci.) (Moscow: M. V. Lomonosov Moscow State University: 1998) (in Russian)
  9. V. H. Ivanchenko, T. V. Pryadko, V. A. Dekhtyarenko, and D. H. Savvakin, Splav dlya Zberigannya Vodnyu, Patent of Ukraine No. 108340 (Publ. April 10, 2015), Bull. No. 7 (in Ukrainian)
  10. V. G. Ivanchenko, V. A. Dekhtyarenko, T. V. Pryadko, and V. I. Nychyporenko, Metallofiz. Noveishie Tekhnol., 36, No. 6: 803 (2014) (in Russian) Crossref
  11. G. F. Kobzenko and A. A. Shkola, Zavod. Laboratoriya, 7: 41 (1990) (in Russian)