Influence of Titanium Content on Interaction Parameters in the Sm$_{2}$Co$_{17-x}$Ti$_{x}$—Н$_{2}$ (x = 1.7; 0.95; 0.5; 0.2; 0.1)
I. I. Bulyk, M. V. Pylat
Karpenko Physico-Mechanical Institute, NAS of Ukraine, 5, Naukova Str., 79060 Lviv, Ukraine
Received: 13.10.2014; final version - 13.04.2015. Download: PDF
Phase transformations in Sm$_{2}$Co$_{17-x}$Ti$_{x}$—Н$_{2}$ (x = 0.1, 0.2, 0.5, 0.95 and 1.7) system are investigated by means of the differential thermal (DTA) and X-ray phase analyses during conventional and solid hydrogenation, disproportionation, desorption, recombination (HDDR) treatment under hydrogen pressure of 3.0—5.2 МPа and temperature up to 950°C. The increase of titanium content leads to the increasing stability of initial ferromagnetic phase with Th$_{2}$Zn$_{17}$-type structure. At х = 0.1 and 0.2, the initial compound completely disproportionates into samarium hydride and cobalt. The partial disproportionation occurs at titanium content х = 0.5. They are found recombined Th$_{2}$Zn$_{17}$-type structure phase, cobalt and traces of samarium oxide after recombination at 850°C in alloys with х = 0.1, 0.2 and 0.5.
Key words: magnetic materials, titanium, alloying, hydrogenation, disproportionation, desorption, recombination, phase transformation.
URL: http://mfint.imp.kiev.ua/en/abstract/v38/i05/0697.html
DOI: https://doi.org/10.15407/mfint.38.05.0697
PACS: 61.05.cp, 64.70.kd, 64.70.Nd, 75.30.Gw, 75.50.Cc, 75.50.Ww, 81.07.Bc
Citation: I. I. Bulyk and M. V. Pylat, Influence of Titanium Content on Interaction Parameters in the Sm$_{2}$Co$_{17-x}$Ti$_{x}$—Н$_{2}$ (x = 1.7; 0.95; 0.5; 0.2; 0.1), Metallofiz. Noveishie Tekhnol., 38, No. 5: 697—707 (2016) (in Ukrainian)