Issues »  Volume 38, Issue 6

Effect of the Active Chemical Elements of Metal-Working Lubricants on Properties of Surface Layers of the Deformed Iron. I. Local Distribution of the Impurity Atoms and Their Nearest Atomic Environment

V. V. Tykhonovych

G.V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03680 Kyiv-142, Ukraine

Received: 10.05.2016. Download: PDF

Effect of the metal-working fluids with active chemical elements on microstructure and phase composition of the rolled iron is studied by the method of transmission electron microscopy. Evolution of the chemical composition of the grain boundaries and their fragments’ boundaries during plastic deformation of the iron in the metal-working fluids with active chemical elements is studied by the Auger electron spectroscopy method. The individual nearest atomic environment of impurity atoms at the grain boundaries and their fragments’ boundaries is studied by the method of high-resolution spectroscopy of the energy losses of the scattered electrons.

Key words: plastic deformation, metal-working fluids, impurity atoms, segregation, atomic clusters, individual atomic environment, disclination.

URL: http://mfint.imp.kiev.ua/en/abstract/v38/i06/0763.html

DOI: https://doi.org/10.15407/mfint.38.06.0763

PACS: 06.60.Vz, 62.20.Qp, 68.35.Dv, 68.37.Lp, 81.07.Bc, 81.40.Lm, 81.40.Pq, 82.80.Pv

Citation: V. V. Tykhonovych, Effect of the Active Chemical Elements of Metal-Working Lubricants on Properties of Surface Layers of the Deformed Iron. I. Local Distribution of the Impurity Atoms and Their Nearest Atomic Environment, Metallofiz. Noveishie Tekhnol., 38, No. 6: 763—781 (2016) (in Russian)

REFERENCES
  1. Yu. M. Vinogradov, Trenie i Iznos Modifitsirovannykh Metallov [Friction and Wear of Modified Metals] (Moscow: Nauka: 1972) (in Russian).
  2. A. A. Gureev, P. P. Zaskal'ko, I. E. Vinogradova, N. M. Mumindzhanov, and V. Kh. Korsunskiy, Khimiya i Tekhnologiya Topliv i Masel, No. 7: 61 (1980) (in Russian).
  3. R. M. Maivievskiy, D. K. Shul'tse, and I. A. Bunyakovskiy, Issledovanie Smazochnykh Materialov pri Trenii. O Svyazi mezhdu Termicheskoy Stabil'nost'yu Khimicheski Aktivnykh Prisadok k Smazochnym Maslam i Ikh Tribotekhnicheskimi Svoystvami pri Trenii [Investigation of Lubricants at Friction. The Connection between the Thermal Stability of Chemically Active Additives to Lubricating Oil and Their Tribological Properties at Friction] (Moscow: Nauka: 1981) (in Russian).
  4. L. M. Roev, L. M. Artyukhovskaya, V. Ya. Sklyar, L. A. Red'ko, and R. A. Svishchuk, Ukrayins'kyy Khimicheskiy Zhurnal, 44, No. 12: 1290 (1978) (in Russian).
  5. V. V. Tykhonovych, V. P. Havrylyuk, V. I. Tykhonovych, and O. M. Hrypachevs'kyy, Metaloznavstvo ta Obrobka Metaliv, No. 1: 12 (2004) (in Ukrainian).
  6. V. V. Gorskiy, V. V. Tikhonovich, Yu. Ya. Meshkov, V. P. Temnenko, B. S. Shapoval, L. M. Sheludchenko, and A. V. Shevchenko, Metallofizika, 12, No. 2: 53 (1990) (in Russian).
  7. V. V. Gorskiy, V. V. Tikhonovich, O. D. Smiyan, S. O. Antonov, and V. I. Franchuk, Metallofizika, 12, No. 3: 89 (1990) (in Russian).
  8. V. V. Tikhonovich, L. M. Sheludchenko, and V. V. Gorskiy, Physicochemical Mechanics of Materials, 26, No. 5: 61 (1990) (in Russian).
  9. L. M. Sheludchenko, V. V. Tikhonovich, V. V. Gorskiy, O. D. Smiyan, S. O. Antonov, and A. D. Drachinskaya, Metallofizika, 14, No. 4: 75 (1992) (in Russian).
  10. V. V. Tikhonovich, V. V. Gorskiy, L. M. Sheludchenko, A. V. Shevchenko, B. S. Shapoval, O. D. Smiyan, S. O. Antonov, and V. P. Temnenko, Physicochemical Mechanics of Materials, 29, No. 1: 100 (1993) (in Russian).
  11. C. L. Briant and R. P. Messmer, Acta Met., 30, No. 2: 457 (1982). Crossref
  12. C. L. Briant and R. P. Messmer, Philos. Mag. B, 42, No. 4: 569 (1980). Crossref
  13. V. S. Urusov, Energeticheskaya Kristallokhimiya [Energy Crystal Chemistry] (Moscow: Nauka: 1975) (in Russian).
  14. D. Briggs and M. P. Sikh, Analiz Poverkhnosti Metodami Auger- i Rentgenovskoy Fotoelektronnoy Spektroskopii [Surface Analysis by Methods of Auger and X-Ray Photoelectron Spectroscopy] (Moscow: Mir: 1987) (in Russian).
  15. K. Masuda-Jindo, phys. status solidi (b), 134: 545 (1986). Crossref
  16. A. I. Kovalev and G. V. Shcherbedinskiy, Sovremennye Metody Issledovaniya Poverkhnosti Metallov i Splavov [Modern Methods of Investigation of Metals and Alloys Surfaces] (Moscow: Metallurgiya: 1989) (in Russian).
  17. A. I. Kovalev, V. P. Mishina, and G. V. Shcherbedinskiy, Metallofizika, 9, No. 3: 112 (1987) (in Russian).
  18. R. L. Blake, R. E. Nessevick, T. Zoltai, and L. W. Finger, American Mineralogist, 51: 123 (1966).

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