Issues »  Volume 40, Issue 4

Influence of Ultrasonic Processing in a Ball Mill on Phase-Structural Characteristics of Superfine Powder Blends of Copper with Iron and Cobalt

V. M. Nadutov, A. O. Perekos, B. M. Mordyuk, V. Z. Voinash, T. V. Efimova, V. P. Zalutsky, T. G. Kabantsev

G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine

Received: 11.01.2018. Download: PDF

Influence of ultrasonic treatment (UST) in a ball mill on structure-phase characteristics and magnetic properties of superfine powder mixtures (SFPM) of copper with iron and cobalt (Cu+Co and Cu+Fe) is investigated by x-ray analysis and magnetic methods. As shown, the UST of SFPM results in decreasing of the Co‒Cu and $\alpha$-Fe‒Cu ferromagnetic phases’ quantity as well as increasing of oxides’ quantity. Dispersity of phase components is in interval 20–50 nm, and concentrations of metals in the Co‒Cu and $\alpha$-Fe‒Cu solid solutions do not change almost. Variations of magnetic properties of SFPM after UST correspond to changing of their phase composition and dispersity: specific saturation magnetization decreases from 64 to 35 A$\cdot$m$^2$/kg, coercivity increases from 2.0 to 20.0 kА/m, and residual magnetization increases from 7.2 to 48.3 mT. As supposed, the peculiarities of structure-phase characteristics of SFPM fabricated by means of the UST are conditioned by presence of the oxide and carbide coatings on particles’ surfaces.

Key words: ultrafine powders blends, electric-spark treatment, ultrasonic milling, x-ray structural analysis, magnetic measurements, magnetic properties.

URL: http://mfint.imp.kiev.ua/en/abstract/v40/i04/0501.html

DOI: https://doi.org/10.15407/mfint.40.04.0501

PACS: 75.50.Tt, 75.75.Cd, 81.07.Wx, 81.20.Ev, 81.20.Wk, 81.40.Rs, 81.70.Jb

Citation: V. M. Nadutov, A. O. Perekos, B. M. Mordyuk, V. Z. Voinash, T. V. Efimova, V. P. Zalutsky, and T. G. Kabantsev, Influence of Ultrasonic Processing in a Ball Mill on Phase-Structural Characteristics of Superfine Powder Blends of Copper with Iron and Cobalt, Metallofiz. Noveishie Tekhnol., 40, No. 4: 501—514 (2018) (in Ukrainian)

REFERENCES
  1. V. M. Nadutov, A. O. Perekos, B. M. Mordyuk, V. Z. Voynash, T. V. Efimova, V. P. Zalutsky, and T. G. Kabantsev, Metallofiz. Noveishie Tekhnol., 40, No. 3: 327 (2018) (in Ukrainian). Crossref
  2. I. D. Morokhov, L. I. Trusov, and S. P. Chizhik, Ultradispersnye Metallicheskie Sredy [Ultrafine Metallic Mediums] (Moscow: Atomizdat: 1967) (in Russian).
  3. A. I. Gusev and A. A. Rempel, Nanokristallicheskie Materialy [Nanocrystalline Materials] (Moscow: Fizmatgiz: 2001) (in Russian).
  4. R. A. Andrievskiy and A. V. Ragulya, Nanostrukturnyye Materialy [Nanostructural Materials] (Moscow: Academiya: 2005) (in Russian).
  5. V. M. Nadutov, A. E. Perekos, V. V. Kokorin, S. M. Konoplyuk, T. V. Yefimova, and V. P. Zalutskiy, Metallofiz. Noveishie Tekhnol., 36, No. 12: 1679 (2014) (in Russian). Crossref
  6. A. V. Bulgakov, N. M. Bulgakova, I. M. Burakov et al., Sintez Nanorazmernykh Materialov pri Vozdeystvii Moshchnykh Potokov Energii na Veshchestvo [Synthesis of Nanosize Materials under Effect of High-Energy Flows on Matter] (Novosibirsk: Institute for Teplofiziki SO RAN: 2009) (in Russian).
  7. V. M. Nadutov, B. N. Mordyuk, G. I. Prokopenko, and I. S. Gavrilenko, Ultrasonics, 42, Iss. 1–9: 47 (2004). Crossref
  8. A. E. Perekos, B. N. Mordyuk, G. I. Prokopenko, T. V. Ruzhitska, T. V. Efimova, V. P. Zalutskiy, and N. D. Rud', Metallofiz. Noveishie Tekhnol., 30, No. 12: 1619 (2008) (in Russian).
  9. V. I. Iveronova and G. P. Revkevich, Teoriya Rasseyaniya Rentgenovskikh Luchey [Theory of X-Ray Scattering] (Moscow: MGU: 1972) (in Russian).
  10. S. S. Gorelik, Yu. A. Skakov, and L. N. Rastorguev, Rentgenograficheskiy i Ehlektronnoopticheskiy Analiz [X-Ray and Electron-Microscopy Analysis) (Moscow: MISiS: 1994) (in Russian).
  11. Ya. S. Umansky and Yu. A. Skakov, Fizika Metallov [Physics of Metals] (Moscow: Atomizdat: 1978) (in Russian).
  12. O. M. Barabash and Yu. N. Koval, Kristallicheskaya Struktura Metallov i Splavov: Spravochnik [Crystalline Structure of Metals and Alloys: Handbook] (Kiev: Naukova Dumka: 1986) (in Russian).
  13. Ya. I. Frenkel, Vvedenie v Teoriyu Metallov [Introduction to Theory of Metals] (Leningrad: Nauka: 1972) (in Russian).
  14. B. G. Livshits, V. S. Kraposhin, and Ya. L. Linetskiy, Fizicheskie Svoystva Metallov i Splavov [Physical Properties of Metals and Alloys] (Moscow: Metallurgiya: 1980) (in Russian).
  15. A. P. Shpak, Yu. A. Kunitskiy, and V. L. Karbovskiy, Klasternye i Nanostrukturnye Materialy [Clustered and Nanostructural Materials] (Kiev: Akademperiodika: 2001) (in Russian).
  16. R. M. Bozorth, Ferromagnetism (Moscow: Inostr. Lit.: 1956) (Russian translation).
  17. S. V. Vonsovsky, Magnetism (Moscow: Nauka: 1971) (in Russian).
  18. W. M. Lomer and W. Marshall, Teoriya Ferromagnetizma Metallov i Splavov [Theory of Ferromagnetism of Metals and Alloys] (Moscow: Inostr. Lit.: 1963), p. 56 (Russian translation).
  19. J. E. Goldman and A. Arrott, Magnitnye Svoystva Metallov i Splavov [Magnetic Properties of Metals and Alloys] (Moscow: Inostr. Lit.: 1961), p. 130 (Russian translation).
  20. G. V. Lutsenko, A. O. Perekos, and A. M. Gusak, Metallofiz. Noveishie Tekhnol., 22, No. 6: 73 (2000) (in Russian).

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