Features of Formation of Structure and Phase Composition During a Reactive Sintering of Cubic Boron Nitride with Compounds of Ti, Cr, V
K. V. Slipchenko1, I. A. Petrusha1, V. Z. Turkevich1, V. M. Bushlya2, J.-E. Stahl2
1V.M. Bakul Institute for Superhard Materials, NAS of Ukraine, 2 Avtozavods’ka Str., UA-04074 Kyiv, Ukraine
2Lund University, Box 117, SE-22100 Lund, Sweden
Received: 18.04.2018. Download: PDF
Influence of sintering temperature on both phase composition and structure of ceramic matrix composites based on cubic boron nitride with binders in a form of Al and the Ti, Cr, V carbides are investigated by methods of physical materials science. As the object of study, three cBN–TiC–Al, cBN–Cr3C2–Al, cBN–VC–Al compositions containing 60% vol. cBN are selected. The composites are obtained by high-pressure high-temperature (HPHT) sintering in high-pressure apparatus AVTT-30 in the temperature range of 1600–2450°C under pressure of 7.7 GPa. In the process of HPHT sintering of composites in the cBN–TiC–Al and cBN–Cr3C2–Al systems, the formation of titanium and chromium diborides is found at the temperatures of sintering Тsint≥ 1850°C and Тsint≥ 2150°C, respectively, simultaneously with the formation of aluminium nitride.
Key words: boron nitride, carbides, ceramic matrix composites, sintering, high pressure.
URL: http://mfint.imp.kiev.ua/en/abstract/v40/i08/1081.html
DOI: https://doi.org/10.15407/mfint.40.08.1081
PACS: 61.05.cp, 61.72.Ff, 62.50.-p, 68.37.Hk, 81.05.Ni, 81.20.Ev, 81.40.Vw
Citation: K. V. Slipchenko, I. A. Petrusha, V. Z. Turkevich, V. M. Bushlya, and J.-E. Stahl, Features of Formation of Structure and Phase Composition During a Reactive Sintering of Cubic Boron Nitride with Compounds of Ti, Cr, V, Metallofiz. Noveishie Tekhnol., 40, No. 8: 1081—1091 (2018) (in Ukrainian)