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Phase Diagrams of Uranium and Its Compounds. I. Destabilization of Ion Shells in Metal. The Quantum Theory

O. I. Mitsek, V. M. Pushkar

G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine

Received: 06.08.2018. Download: PDF

Metallic U is calculated by means of the method of many-electron operator spinors. Atomic phase diagram is accompanied by dividing of 5f-shell on eg (5f1) and t2g (5f2) subshells. Destabilization of U ion electronic structure is connected with 5f–6d hybridization. Jumping of ‘outer’ 5f1 electrons on 6d level owing to excitation of chemical (covalent) bond fluctuations (CBF) with temperature T growth leads to αβ transition (TTk1). Then growth of CBF density excites 5f2–6d hybridization and βγ transition at TTk2 > Tk1. Hysteresis of each transition is conditioned by covalent-band bonds. Transitional volume jumps ΔV1,2 are determined by inhomogeneity Γdd(rR) of U ion covalent bonds in sites \textbf{r} and \textbf{R}. Angular moment \textbf{L}_{\textbf{r}} locality prevents from display magnetism of metallic U. But inclusion of U ion spin-orbital bonds with 3d ions influences on magnetic hardness of alloys of U–Co type, which is observed experimentally.

Key words: chemical bond fluctuations (CBF), destabilization of the 5f shell and phase transitions, Galois groups.

URL: http://mfint.imp.kiev.ua/en/abstract/v41/i03/0279.html

DOI: https://doi.org/10.15407/mfint.41.03.0279

PACS: 61.50.Ks, 71.10.-w, 71.20.Gj, 71.30.+h, 75.10.Dg, 75.30.Et, 75.30.Mb

Citation: O. I. Mitsek and V. M. Pushkar, Phase Diagrams of Uranium and Its Compounds. I. Destabilization of Ion Shells in Metal. The Quantum Theory, Metallofiz. Noveishie Tekhnol., 41, No. 3: 279—288 (2019) (in Russian)


REFERENCES
  1. K. J. Smitlz, Metally [Metals] (Moscow: Metallurgiya: 1980) (in Russian).
  2. A. V. Deryagin and A. V. Andreev, ZhETF, 71, No. 9: 1166 (1976) (in Russian).
  3. O. I. Mitsek and V. M. Pushkar, Metallofiz. Noveishie Tekhnol., 37, No. 4: 433 (2015) (in Russian). Crossref
  4. O. I. Mitsek, Metallofiz. Noveishie Tekhnol., 23, No. 1: 1 (2001) (in Russian).
  5. K. P. Belov, Z. Genke, and A. S. Dmitrievskiy, ZhETF, 64, No. 5: 583 (1973) (in Russian).
  6. R. Z. Levitin, A. S. Dmitrievsri, Z. Henke, and A. Misiuk, phys. status solidi (a), 27, Iss. 2: K109 (1975). Crossref
  7. O. I. Mitsek and V. M. Pushkar, Metallofiz. Noveishie Tekhnol., 39, No. 4: 425 (2017) (in Russian). Crossref
  8. O. I. Mitsek and V. M. Pushkar, Metallofiz. Noveishie Tekhnol., 38, No. 7: 853 (2016) (in Russian). Crossref