Structure and Mechanical Properties of Al–Cu/C Composites Produced by Mechanical Alloying and Solid-State Sintering
Ya. I. Matvienko1, S. S. Polishchuk1, A. D. Rud1, T. M. Mika1, V. I. Bondarchuk1, S. A. Demchenkov2
1G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine
2E. O. Paton Electric Welding Institute, NAS of Ukraine, 11 Kazymyr Malevych Str., UA-03150 Kyiv, Ukraine
Received: 12.05.2019. Download: PDF
Hypoeutectic and eutectic Al–Cu composites with 5% wt. of graphite additives are prepared using mechanical alloying (MA) of elemental powders and following hot pressing of mixtures at 480–510°C and 30 MPa. The obtained powders and sintered samples are studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), and differential scanning calorimetry (DSC). The MA during 8 hours of all powder compositions results in the formation of Cu9Al4 and CuAl2 phases as well as Al(Cu) solid solution. Subsequent sintering leads to the decomposition of the metastable Cu9Al4 phase. As shown, the crystalline structure of graphite additives transforms into amorphous one during MA, while the consequent sintering results in the Al4C3 carbide formation. Moreover, the introduction of graphite additives leads to increasing of both the highly dispersed particles amount in mechanically alloyed powder and the volume fraction of metastable Cu9Al4 and stable CuAl2 intermetallic phases. The effects of both graphite additives and Cu content (17 and 33% wt.) on microstructure and mechanical properties of sintered Al–Cu composites are considered. Possible strengthening mechanisms for Al–Cu and Al–Cu/C composites are discussed.
Key words: Al–Cu/C, metal matrix composites, mechanical alloying, solid-state sintering, powder metallurgy.
URL: http://mfint.imp.kiev.ua/en/abstract/v41/i08/1035.html
DOI: https://doi.org/10.15407/mfint.41.08.1035
PACS: 61.05.cp, 62.25.-g, 64.60.My, 64.70.kd, 81.20.Ev, 81.20.Wk
Citation: Ya. I. Matvienko, S. S. Polishchuk, A. D. Rud, T. M. Mika, V. I. Bondarchuk, and S. A. Demchenkov, Structure and Mechanical Properties of Al–Cu/C Composites Produced by Mechanical Alloying and Solid-State Sintering, Metallofiz. Noveishie Tekhnol., 41, No. 8: 1035—1054 (2019) (in Ukrainian)