Issues »  Volume 41, Issue 11

Structure, Phase Composition and Hydrogen Adsorption Properties of Eutectic Alloys of the Ti–Zr–Mn–V System

V. A. Dekhtyarenko, T. V. Pryadko, D. G. Savvakin, T. A. Kosorukova

G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine

Received: 07.08.2019. Download: PDF

The microstructure and phase composition of the Ti–Zr–Mn–V eutectic alloys in the cast state, as well as the phase composition of the hydrogenation product, are studied using scanning electron microscopy and X-ray phase analysis. As established, a vanadium doping in eutectic alloys 47.5Ti–30Zr–22.5Mn shifts the eutectic binodal towards the b.c.c. solid solution, thereby expanding the region of existence of the Laves phase. As shown, during the interaction of alloys with hydrogen (Sivert’s method) hydrides are formed only on the basis of coexisting phases, and the distribution of vanadium in phases leads to an increase in the sorption capacity of both the b.c.c. solid solution and the Laves phase.

Key words: Laves phase, b.c.c. solid solution, eutectic, hydrogenation, hydrogen.

URL: http://mfint.imp.kiev.ua/en/abstract/v41/i11/1455.html

DOI: https://doi.org/10.15407/mfint.41.11.1455

PACS: 61.66.Dk, 61.72.Yx, 64.75.-g, 68.43.Mn, 82.30.Rs, 82.80 Ms

Citation: V. A. Dekhtyarenko, T. V. Pryadko, D. G. Savvakin, and T. A. Kosorukova, Structure, Phase Composition and Hydrogen Adsorption Properties of Eutectic Alloys of the Ti–Zr–Mn–V System, Metallofiz. Noveishie Tekhnol., 41, No. 11: 1455—1468 (2019) (in Russian)

REFERENCES
  1. Fundamental'ni Aspekty Vidnovlyuvano-Vodnevoyi Energetyky i Palyvno-Komirchanykh Tekhnolohiy [Fundamental Aspects of Renewable Hydrogen Energy and Fuel cell Technologies] (Ed. Y. M. Solonin) (Kyiv: KIM: 2018).
  2. V. Ivanchenko, T. Pryadko, I. Gavrylenko, and V. Pogorelaya, Chem. Metals Alloys, 1, No. 1: 67 (2008).
  3. V. Ivanchenko, T. Pryadko, V. Dekhtyarenko, and T. Kosorukova, Chem. Metals Alloys, 1, No. 2: 133 (2008).
  4. V. G. Ivanchenko, V. A. Dekhtyarenko, and T. V. Pryadko, Metaloznavstvo Obrobka Metaliv, No. 1: 4 (2010) (in Ukrainian).
  5. V. G. Ivanchenko, V. A. Dekhtyarenko, and T. V. Pryadko, Metallofiz. Noveishie Tekhnol., 33, No. 11: 479 (2011) (in Russian).
  6. Y. Nakamura, O. Kenich, T. Kamiyama, and E. Akiba, J. Alloys Compd., 316: 284 (2001). Crossref
  7. H. Taizhong, W. Zhu, S. Guoxin, and X. Naixin, Intermetallics, 15: 593 (2007). Crossref
  8. X. Y. Chen, R. R. Chen, X. Ding, H. Z. Fang, J. J. Guo, H. S. Ding, Y. Q. Su, and H. Z. Fu, Int. J. Hydrogen Energy, 43, No. 12: 6210 (2018). Crossref
  9. E. Akiba and H. Iba, Intermetallics, 6: 461 (1998). Crossref
  10. E. A. Anikina and V. N. Verbetsky, International J. Hydrogen Energy, 36, No. 1: 1344 (2011). Crossref
  11. S. V. Mitrokhin, T. N. Bezuglaya, and V. N. Verbetsky, J. Alloys Compd., 330-332: 146 (2002). Crossref
  12. Y. Shudo, T. Ebisawa, and H. Itoh, J. Alloys Compd., 356-357: 497 (2003). Crossref
  13. M. Ping, W. Erdong, and L. Wuhui, Int. J. Hydrogen Energy, 39, No. 25: 13569 (2014). Crossref
  14. V. G. Ivanchenko, V. A. Dekhtyarenko, and T. V. Pryadko, Metallofiz. Noveishie Tekhnol., 36, No. 6: 803 (2014) (in Russian). Crossref
  15. V. G. Ivanchenko, V. A. Dekhtyarenko, and T. V. Pryadko, Metallofiz. Noveishie Tekhnol., 37, No. 4: 521 (2015). Crossref
  16. V. G. Ivanchenko, V. A. Dekhtyarenko, T. V. Pryadko, D. G. Savvakin, and I. K. Evlash, Mater. Sci., 51, No. 4: 492 (2016). Crossref
  17. T. V. Pryadko, Metallofiz. Noveishie Tekhnol., 37, No. 2: 243 (2015) (in Russian). Crossref
  18. G. F. Kobzenko and A. A. Shkola, Zavodskaya Laboratoriya, 7: 41 (1990) (in Russian).

© 2013–2019 "G.V. Kurdyumov Institute for Metal Physics"