In this paper, we predict the adhesion energy terms in metal/ceramic systems by using acoustic parameters of these combinations. Different approaches are used. Semiempirical relations are deduced for all systems. As shown, in all cases, the adhesion energy $W_{\textrm{ad}}$ increases linearly with Rayleigh velocity of ceramic substrate $V_{RC}$. It takes the form $W_{\textrm{ad}}$ = 0.07$V_{RC}$ + $C$, where the first term of this equation represents the van der Waals contribution to $W_{\textrm{ad}}$, which only depends on $V_{RC}$. The second term represents the equilibrium chemical bonds contribution ($W_{\textrm{chem-equil}}$) and strongly depends on the systems combination as well as on the energy gap of the ceramics substrate. Moreover, the $W_{\textrm{chem-equil}}$ energy is higher for small bandgap ceramic materials due to substantial charge carriers’ density inside ceramic crystal and, consequently, ease and height electron transfer through the metal/ceramic interface. In this case, the $W_{\textrm{chem-equil}}$ is essentially depends on Rayleigh velocity $V_{RM}$ of deposited metal. For large bandgap ceramic materials, there are practically no free charges inside ceramic crystal. In this case, the electrons’ transfer cannot be taking place and, as a result, the $W_{\textrm{chem-equil}}$ contribution is negligible. The importance of obtained relation lies in its universality and applicability to all investigated systems.