Magnetic and Photocatalytic Properties of Nanodispersed Ferrites CoxNiyZn1−x−yFe2O4
L. A. Frolova1, O. V. Khmelenko2, O. S. Kovrov3
1SHEI ‘Ukrainian State University of Chemical Technology’, 8 Gagarin Ave., UA-49005 Dnipro, Ukraine
2Oles Honchar Dnipro National University, 72 Gagarin Ave., UA-49010 Dnipro, Ukraine
3National Technical University ‘Dnipro Polytechnic’, 19 Dmytro Yavornytsky Ave., UA-49005 Dnipro, Ukraine
Received: 18.07.2020; final version - 07.12.2020. Download: PDF
The dependence of the magnetic and photocatalytic properties of the ferrites of CoxNiyZn1−x−yFe2O4 composition (where 0 < x < 1 and 0 < y < 1) is considered. The ferrites are synthesized by the plasma method in the form of nanoparticles. A study of the nanoferrites properties of is performed using X-ray phase analysis, vibration magnetometry, and spectroscopy. Photocatalytic properties in the decomposition reaction of methylene blue are determined by UV-spectrograms. Mathematical equations of the dependences of the response functions on the composition are obtained using the simplex method. As found, the saturation magnetization decreases for ferrites of Ni1−xZnxFe2O4 and Co1−xFe2O4 compositions with increasing zinc cation content. For a number of Ni1−xCoxFe2O4 ferrites, increased magnetic characteristics are observed. The study of catalytic activity against the decomposition reaction of methylene blue shows high photocatalytic properties for double and triple ferrites. A correlation between the photocatalytic activity and the band gap energy is determined.
Key words: ferrites, plasma method, simplex method, saturation magnetization, photocatalysis, coercive force.
URL: http://mfint.imp.kiev.ua/en/abstract/v43/i02/0159.html
DOI: https://doi.org/10.15407/mfint.43.02.0159
PACS: 52.77.Dq, 61.05.cp, 61.46.-w, 61.66.Fn, 75.50.Gg, 75.60.Ej, 81.20.Fw
Citation: L. A. Frolova, O. V. Khmelenko, and O. S. Kovrov, Magnetic and Photocatalytic Properties of Nanodispersed Ferrites CoxNiyZn1−x−yFe2O4, Metallofiz. Noveishie Tekhnol., 43, No. 2: 159—171 (2021) (in Ukrainian)