Magnetic and Photocatalytic Properties of Nanodispersed Ferrites Co$_x$Ni$_y$Zn$_{1-x-y}$Fe$_2$O$_4$

L. A. Frolova$^{1}$, O. V. Khmelenko$^{2}$, O. S. Kovrov$^{3}$

$^{1}$SHEI ‘Ukrainian State University of Chemical Technology’, 8 Gagarin Ave., UA-49005 Dnipro, Ukraine
$^{2}$Oles Honchar Dnipro National University, 72 Gagarin Ave., UA-49010 Dnipro, Ukraine
$^{3}$National Technical University ‘Dnipro Polytechnic’, 19 Dmytro Yavornytsky Ave., UA-49005 Dnipro, Ukraine

Received: 18.07.2020; final version - 07.12.2020. Download: PDF

The dependence of the magnetic and photocatalytic properties of the ferrites of Co$_x$Ni$_y$Zn$_{1-x-y}$Fe$_2$O$_4$ composition (where 0 < $x$ < 1 and 0 < $y$ < 1) is considered. The ferrites are synthesized by the plasma method in the form of nanoparticles. A study of the nanoferrites properties of is performed using X-ray phase analysis, vibration magnetometry, and spectroscopy. Photocatalytic properties in the decomposition reaction of methylene blue are determined by UV-spectrograms. Mathematical equations of the dependences of the response functions on the composition are obtained using the simplex method. As found, the saturation magnetization decreases for ferrites of Ni$_{1-x}$Zn$_x$Fe$_2$O$_4$ and Co$_{1-x}$Fe$_2$O$_4$ compositions with increasing zinc cation content. For a number of Ni$_{1-x}$Co$_x$Fe$_2$O$_4$ ferrites, increased magnetic characteristics are observed. The study of catalytic activity against the decomposition reaction of methylene blue shows high photocatalytic properties for double and triple ferrites. A correlation between the photocatalytic activity and the band gap energy is determined.

Key words: ferrites, plasma method, simplex method, saturation magnetization, photocatalysis, coercive force.

URL: http://mfint.imp.kiev.ua/en/abstract/v43/i02/0159.html

DOI: https://doi.org/10.15407/mfint.43.02.0159

PACS: 52.77.Dq, 61.05.cp, 61.46.-w, 61.66.Fn, 75.50.Gg, 75.60.Ej, 81.20.Fw

Citation: L. A. Frolova, O. V. Khmelenko, and O. S. Kovrov, Magnetic and Photocatalytic Properties of Nanodispersed Ferrites Co$_x$Ni$_y$Zn$_{1-x-y}$Fe$_2$O$_4$, Metallofiz. Noveishie Tekhnol., 43, No. 2: 159—171 (2021) (in Ukrainian)


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