Structure Phase State and Properties of Аl–6Мg Alloy after Electric Discharge Alloying with Tungsten and Ultrasonic Finishing

V. V. Mohylko$^{1}$, A. P. Burmak$^{1}$, S. M. Voloshko$^{1}$, S. I. Sidorenko$^{1}$, B. N. Mordyuk$^{2,1}$

$^{1}$National Technical University of Ukraine ‘Igor Sikorsky Kyiv Polytechnic Institute’, 37 Peremohy Ave., UA-03056 Kyiv, Ukraine
$^{2}$G. V. Kurdyumov Institute for Metal Physics, NAS of Ukraine, 36 Academician Vernadsky Blvd., UA-03142 Kyiv, Ukraine

Received: 07.04.2022. Download: PDF

The efficiency of modification of the surface layers of Al–6Mg aluminium alloy by combined treatment, including electric discharge surface alloying (EDSA) with Tungsten and finishing ultrasonic impact treatment (UIT) to improve the microstructure, strength and corrosion properties is analysed. The results of electron microscopic and x-ray structural phase analyses indicate the formation of the surface layer containing Al–W solid solution and Al$_{4}$W or Al$_{12}$W intermetallic phases, which cause hardening. Micro-durometric analysis shows that the combined (EDSA (W) + UIT) process doubled the microhardness of the surface layers as compared to the initial state. As shown, the modified surface possesses the increased anti-corrosion properties owing to the accelerated formation of the passivating oxide film due to the large number of intergranular and interfacial boundaries.

Key words: aluminium alloy, ultrasonic impact treatment, electric discharge alloying, microstructure, microhardness, corrosion.

URL: https://mfint.imp.kiev.ua/en/abstract/v44/i05/0639.html

DOI: https://doi.org/10.15407/mfint.44.05.0639

PACS: 43.35.+d, 61.72.Ff, 81.40.-z, 81.65.-b, 81.65.Kn, 83.10.Tv

Citation: V. V. Mohylko, A. P. Burmak, S. M. Voloshko, S. I. Sidorenko, and B. N. Mordyuk, Structure Phase State and Properties of Аl–6Мg Alloy after Electric Discharge Alloying with Tungsten and Ultrasonic Finishing, Metallofiz. Noveishie Tekhnol., 44, No. 5: 639—658 (2022) (in Ukrainian)


REFERENCES
  1. K. Dai, J. Villegas, Z. Stone, and L. Shaw, Acta Mater., 52: 5771 (2004). Crossref
  2. U. Trdan, M. Skarba, and J. Grum, Mater. Characterization, 97: 57 (2014). Crossref
  3. M. O. Vasyl'yev, B. M. Mordyuk, S. I. Sydorenko, S. M. Voloshko, and A. P. Burmak, Metallofiz. Noveishie Tekhnol., 37, No. 9: 1269 (2015) (in Ukrainian). Crossref
  4. R. S. Mishra, Z. Y. Ma, and I. Charit, Mater. Sci. Eng. A, 341: 307 (2003). Crossref
  5. V. G. Efremenko, K. Shimizu, T. V. Pastukhova, Yu. G. Chabak, K. Kusumoto, and A. V. Efremenko, Trenie i Iznos, 38, No. 1: 24 (2017) (in Russian). Crossref
  6. M. O. Vasyl'yev, B. M. Mordyuk, S. I. Sydorenko, S. M. Voloshko, A. P. Burmak, and M. V. Kindrachuk, Metallofiz. Noveishie Tekhnol., 38, No. 4: 545 (2016) (in Ukrainian). Crossref
  7. B. N. Mordyuk, G. I. Prokopenko, Y. V. Milman, M. O. Iefimov, and A. V. Sameljuk, Mater. Sci. Eng. A, 563: 138 (2013). Crossref
  8. B. N. Mordyuk, G. I. Prokopenko, Y. V. Milman, M. O. Iefimov, K. E. Grinkevych, A. V. Sameljuk, and I. V. Tkachenko, Wear, 319: 84 (2014). Crossref
  9. B. N. Mordyuk, V. V. Silberschmidt, G. I. Prokopenko, Y. V. Nesterenko, and M. O. Iefimov, Mater. Characterization, 61: 1126 (2010). Crossref
  10. M. A. Vasylyev, B. N. Mordyuk, S. I. Sidorenko, S. M. Voloshko, and A. P. Burmak, Surf. Eng., 34: 324 (2018). Crossref
  11. M. A. Mũnoz-Morris, N. Calderón, I. Gutierrez-Urrutia, and D. G. Morris, Mater. Sci. Eng. A, 425: 131 (2006). Crossref
  12. M. Reboul and B. Baroux, Mater. Corrosion, 62: 215 (2011). Crossref
  13. J. Skrovan, A. Alfantazi, and T. Troczynski, J. Appl. Electrochem., 39: 1695 (2009). Crossref
  14. Z. Szklarska-Smialowska, Corros. Sci., 41: 1743 (1999). Crossref
  15. J. R. Davis, Corrosion of Aluminum and Aluminum Alloys (ASM International (OH): 1999). Crossref
  16. O. V. Maksakova, O. D. Pogrebnjak, and V. M. Beresnev, Usp. Fiz. Met., 19, No. 1: 25 (2018). Crossref
  17. M. A. Vasylyev, B. N. Mordyuk, S. I. Sidorenko, S. M. Voloshko, A. P. Burmak, I. O. Kruhlov, and V. I. Zakiev, Surf. Coat. Technol., 361: 413 (2019). Crossref
  18. I. P. Shats'kyy, L. Ya. Rop'yak, and M. M. Makoviychuk, Problemy Mitsnosti, No. 5: 163 (2016) (in Ukrainian).
  19. B. N. Mordyuk, S. M. Voloshko, V. I. Zakiev, A. P. Burmak, and V. V. Mohylko, J. Mater. Eng. Perform., 30: 1780 (2021). Crossref
  20. B. M. Mordyuk, S. M. Voloshko, A. P. Burmak, V. V. Mohylko, M. M. Voron, Metallofiz. Noveishie Tekhnol., 41, No. 8: 1067 (2019) (in Ukrainian). Crossref
  21. V. F. Mazanko, D. S. Gertsriken, S. A. Bobyr', V. M. Mironov, and D. V. Mironov, Iskrovoy Razryad i Diffuzionnye Protsessy v Metallakh [Spark Discharge and Diffusion Processes in Metals] (Kyiv: Naukova Dumka: 2014) (in Russian).
  22. B. M. Mordyuk, S. M. Voloshko, A. P. Burmak, and D. S. Malakhov, Metallofiz. Noveishie Tekhnol., 42, No. 7: 997 (2020) (in Ukrainian). Crossref
  23. M. A. Vasylyev, B. N. Mordyuk, V. P. Bevz, S. M. Voloshko, and O. B. Mordiuk, Int. J. Surf. Sci. Eng., 14, No. 1: 1 (2020). Crossref
  24. V. V. Mohylko, A. P. Burmak, S. M. Voloshko, C. I. Sydorenko, and B. M. Mordyuk, Metallofiz. Noveishie Tekhnol., 44, No. 2: 223 (2022) (in Ukrainian). Crossref
  25. N. Stoloff, C. Liu, and S. Deevi, Intermetallics, 8: 1313 (2000). Crossref
  26. E. Principe, B. Shaw, and G. Davis, Corrosion, 59: 295 (2003). Crossref
  27. B. N. Mordyuk, G. I. Prokopenko, K. E. Grinkevych, N. A. Piskun, and T. V. Popova, Surf. Coat. Technol., 309: 969 (2017). Crossref
  28. H. Zhang, P. Feng, and F. Akhtar, Sci. Rep., 7: 12391 (2017). Crossref
  29. D. Chen, Z. Chen, J. Cai, and Z. Chen, J. Alloy. Compd., 461: L23 (2008). Crossref
  30. C. Unuvar, D. Fredrick, U. Anselmi-Tamburini, B. Shaw, A. Manerbino, J. Guigné, and Z. Munir, Intermetallics, 15: 294 (2007). Crossref
  31. S. Varam, P. V. S. L. Narayana, M. D. Prasad, D. Chakravarty, K. V. Rajulapati, and K. B. S. Rao, Phil. Mag. Let., 94: 582 (2014). Crossref
  32. A. Hu and S. Cai, J. Mater. Res. Technol., 13: 311 (2021). Crossref
  33. T. Cegan, D. Petlak, K. Skotnicova, J. Jurica, B. Smetana, and S. Zla, Molecules, 25: 2001 (2020). Crossref
  34. G. D. Davis, B. A. Shaw, B. J. Rees, and M. Ferry, J. Electrochem. Soc., 140: 951 (1993). Crossref
  35. R. S. Rajamure, H. D. Vora, S. G. Srinivasan, and N. B. Dahotre, Appl. Surf. Sci., 328: 205 (2015). Crossref
  36. L. Iglesias-Rubianes, P. Skeldon, G. E. Thompson, H. Habazaki, and K. Shimizu, Phil. Mag. A, 81: 1579 (2001). Crossref
  37. D. K. Merl, P. Panjan, and J. Kovač, Corros. Sci., 69: 359 (2013). Crossref
  38. N. I. Lazarenko, Elektroiskrovoe Legirovanie Metallicheskikh Poverkhnostey [Electric Spark Alloying of Metallic Surfaces] (Moscow: Mashinostroenie: 1976) (in Russian).
  39. Z. Zhang and D. L. Chen, Scripta Mater., 54: 1321 (2006). Crossref