Influence of Hydrogen on Plate Deformation during Formation of Gradient Alloy of Palladium with Hydrogen

O. M. Lyubimenko

Donetsk National Technical University, 2 Shybankov Sqr., UA-85300 Pokrovs’k, Ukraine

Received: 06.05.2022; final version - 13.06.2022. Download: PDF

In this work the study and analysis of video recording of bending experiment of pure palladium plate and plate of $\alpha$-PdH$_{0.0071}$ at 200°C with increasing hydrogen concentration in palladium by $\Delta n$ = 0.00355$i$, where $i$ = 1, 2, 3, 4 and time graded alloys $\alpha$-PdH$_{0.00355}$, $\alpha$-PdH$_{0.0071}$, $\alpha$-PdH$_{0.0105}$, $\alpha$-PdH$_{0.0142}$, $\alpha$-PdH$_{0.0177}$, $\alpha$-PdH$_{0.0213}$ H/Pd are obtained. It is experimentally established for the first time that at 200°C with increasing concentration by $\Delta n$ = 0.00355H/Pd the maximum plate bends for the $\alpha$-PdH$_{n}$ alloy are larger than those for the pure palladium plate and are almost completely reversed in the range from 0 to 0.16 mm for both plates. In the experiments it is first recorded that at 200°C when the maximum bending of the $\alpha$-PdH$_{n}$ alloy plate is reached, a slowing down of the plate bending process is observed with reaching a plateau of duration in each experiment of 4 to 7 s. It is experimentally confirmed that at $T$ = 200°C the physical nature of the appearance in the first seconds of the maximum bending of the plate is due to the formation of temporary gradient $\alpha$-PdH$_{n}$ alloy with layers of a certain thickness that have other physical properties than pure palladium. And also, a change in the kinetics of hydrogen transport inside for the plate from the $\alpha$-PdH$_{0.0071}$ alloy, due to a change in the mechanism of distribution and occurrence of hydrogen-concentration stresses in the plate from the $\alpha$-PdH$_{0.0071}$ alloy is fixed during the formation of the maximum bend.

Key words: bending, hydrogen, palladium, $\alpha$-PdH$_{n}$ gradient alloy, concentration.

URL: https://mfint.imp.kiev.ua/en/abstract/v44/i07/0899.html

DOI: https://doi.org/10.15407/mfint.44.07.0899

PACS: 62.20.-x, 64.80.-v, 66.30.-h, 68.43.-h, 81.05.Bx, 81.40.-z

Citation: O. M. Lyubimenko, Influence of Hydrogen on Plate Deformation during Formation of Gradient Alloy of Palladium with Hydrogen, Metallofiz. Noveishie Tekhnol., 44, No. 7: 899—911 (2022) (in Ukrainian)


REFERENCES
  1. Y. H. Lee, Y. Jang, D. H. Han, S. M. Lee, and S. S. Kim, J. Environmental Chemical Engineering, 9, Iss. 6: 106509 (2021). Crossref
  2. Zhengzhao Han, Ke Xu, Ningbo Liao, and Wei Xue, Int. J. Hydrogen Energy, 46, No. 46: 23715 (2021). Crossref
  3. Mostafa El-Shafie, Shinji Kambra, and Yukio Hayakawa, South African J. Chemical Engineering, 35: 118 (2021). Crossref
  4. V. A. Goltsov, Progress in Hydrogen Treatment of Materials (Donetsk: Kassiopeya Ltd.: 2001), p. 3.
  5. Zh. L. Glukhova, V. A. Goltsov, T. A. Schegoleva, R. V. Kotelva, and O. M. Lyubimenko, Int. J. Nuclear Hydrogen Production and Applications, 1, No. 4: 334 (2008). Crossref
  6. V. A. Gol'tsov, E. N. Lyubimenko, and Zh. L. Glukhova, Physicochemical Mechanics of Materials, 45, No. 5: 55 (2009) (in Russian). Crossref
  7. O. M. Lyubimenko and O. A. Shtepa, Metallofiz. Noveishie Tekhnol., 43, No. 12: 1639 (2021) (in Ukrainian). Crossref
  8. E. Wicke, H. Brodowsky, and H. Züchner, Vodorod v Metallakh [Hydrogen in Metals] (Eds. G. Alefeld and J. Völkl) (Moscow: Mir: 1981), vol. 2, p. 91 (in Russian).
  9. A. I. Raychenko, Matematicheskaya Teoriya Diffuzii v Prilozheniyakh [Mathematical Theory of Diffusion in Applications] (Kyiv: Naukova Dumka: 1981) (in Russian).
  10. E. P. Feldman, E. N. Lyubimenko, and K. V. Gumennyk, J. Applied Physics, 127, No. 24: 245104 (2020). Crossref