Influence of Hydrogen on Plate Deformation during Formation of Gradient Alloy of Palladium with Hydrogen
O. M. Lyubimenko
Донецкий национальный технический университет, пл. Шибанкова, 2, 85300 Покровск, Украина
Получена: 06.05.2022; окончательный вариант - 13.06.2022. Скачать: PDF
In this work the study and analysis of video recording of bending experiment of pure palladium plate and plate of α-PdH0.0071 at 200°C with increasing hydrogen concentration in palladium by Δn = 0.00355i, where i = 1, 2, 3, 4 and time graded alloys α-PdH0.00355, α-PdH0.0071, α-PdH0.0105, α-PdH0.0142, α-PdH0.0177, α-PdH0.0213 H/Pd are obtained. It is experimentally established for the first time that at 200°C with increasing concentration by Δn = 0.00355H/Pd the maximum plate bends for the α-PdHn alloy are larger than those for the pure palladium plate and are almost completely reversed in the range from 0 to 0.16 mm for both plates. In the experiments it is first recorded that at 200°C when the maximum bending of the α-PdHn alloy plate is reached, a slowing down of the plate bending process is observed with reaching a plateau of duration in each experiment of 4 to 7 s. It is experimentally confirmed that at T = 200°C the physical nature of the appearance in the first seconds of the maximum bending of the plate is due to the formation of temporary gradient α-PdHn alloy with layers of a certain thickness that have other physical properties than pure palladium. And also, a change in the kinetics of hydrogen transport inside for the plate from the α-PdH0.0071 alloy, due to a change in the mechanism of distribution and occurrence of hydrogen-concentration stresses in the plate from the α-PdH0.0071 alloy is fixed during the formation of the maximum bend.
Ключевые слова: bending, hydrogen, palladium, α-PdHn gradient alloy, concentration.
URL: https://mfint.imp.kiev.ua/ru/abstract/v44/i07/0899.html
PACS: 62.20.-x, 64.80.-v, 66.30.-h, 68.43.-h, 81.05.Bx, 81.40.-z