Electrophysical Characteristics of cBN–NbN Composite Ceramics Doped with Al2O3, Si3N4, and SiC
Yu. Yu. Rumyantseva1,2, L. O. Romanko1, I. P. Fesenko1, D. O. Savchenko1, V. Z. Turkevych1, S. Karcz2
1Институт сверхтвёрдых материалов им. В. Н. Бакуля НАН Украины, ул. Автозаводская, 2, 04074 Киев, Украина
2Łukasiewicz - Krakow Institute of Technology, 73 Zakopińska Str, 30-011 Krakow, Poland
Получена: 19.02.2023; окончательный вариант - 13.04.2023. Скачать: PDF
Different additives’ influence on electric conductivity of ‘dielectric/conductor’-type composites (namely, polycrystalline cBN-based composites contained cBN as a dielectric phase and NbN as a conductor phase) is investigated. Investigated samples are obtained by the application of HPHT (high pressure-high temperature) sintering (P = 7.7 GPa, T = 2000°C). Electrical-resistance dependences on the temperature and applied voltage are measured for all samples. Obtained results’ analysis shows that all sintered samples have a semiconductor nature of conductivity. It is interesting that addition dielectrics (Al2O3, Si3N4) as well as semiconductor (SiC) leads to the electric-conductivity improve (drop in electrical resistance) for cBN–NbN composites in some degree (despite the lower electrical conductivity of these substances). Alumina whiskers’ addition to cBN–NbN composites leads to a more significant drop in electrical resistance compared to powder particles’ addition (from 1.85 to 0.72 Ohm⋅cm for samples with whiskers (Al2O3w) and from 1.35 to 0.17 Ohm⋅cm for samples with Al2O3 powder). Hence, as concluded, the sample electrical conductivity is affected by both the additive particles’ morphology and the grain boundaries’ state of the sintered polycrystalline ceramics.
Ключевые слова: dielectric, cBN, conductor, NbN, composite, additives, Al2O3, Si3N4, SiC, electrical resistance.
URL: https://mfint.imp.kiev.ua/ru/abstract/v45/i06/0723.html
PACS: 72.60.+g, 72.80.Ey, 72.80.Tm, 81.05.Je, 81.05.Mh, 81.40.Rs, 81.70.-q