Effect of Peculiarities of Thermal Stabilization on Structure and Electrical Conductivity of Copper, Gold, and Silver Nanofilms

R. I. Bihun$^{1}$, Z. V. Stasyuk$^{1}$, M. D. Buchkovs’ka$^{1}$, V. M. Gavrylukh$^{1}$, D. S. Leonov$^{2}$

$^{1}$Ivan Franko National University of Lviv, 1 Universytets’ka Str., UA-79000 Lviv, Ukraine
$^{2}$Technical Centre, NAS of Ukraine, 13 Pokrovs’ka Str., UA-04070 Kyiv, Ukraine

Received: 27.10.2020. Download: PDF

The effect of the thermal stabilization regime within the first temperature zone of Movchan–Demchishin model of the formation of films on the structure and electrical conductivity of silver, copper, and gold films formed under ultrahigh vacuum conditions by the method of frozen condensation of a thermally evaporated metal vapour on amorphous dielectric substrates, preliminarily coated with underlayers of subatomic thickness, is investigated. The possibility of stepless control of the average linear dimensions of crystallites in a metal condensate is confirmed by joint use of a surfactant underlayer of a substance (germanium), which counteracts the coalescence of metal crystallization nuclei, and the choice of a film thermal stabilization mode. A theoretical description of the dimensional dependences of the electrical conductivity of films is implemented using the created theoretical models.

Key words: thin metal films, underlayers of subatomic thickness, electrical conductivity of films, thermal stabilization, zone of Movchan–Demchyshyn.

URL: http://mfint.imp.kiev.ua/en/abstract/v42/i12/1629.html

DOI: https://doi.org/10.15407/mfint.42.12.1629

PACS: 64.60.ah, 68.35.bd, 73.61.At, 73.63.Bd, 81.15.Kk

Citation: R. I. Bihun, Z. V. Stasyuk, M. D. Buchkovs’ka, V. M. Gavrylukh, and D. S. Leonov, Effect of Peculiarities of Thermal Stabilization on Structure and Electrical Conductivity of Copper, Gold, and Silver Nanofilms, Metallofiz. Noveishie Tekhnol., 42, No. 12: 1629—1639 (2020) (in Ukrainian)


REFERENCES
  1. B. A. Movchan and A. V. Demchishin, Fizika Metallov i Metallovedenie, 28, Iss. 4: 653 (1969) (in Russian).
  2. D. Gall, J. Appl. Phys., 119: 085101 (2016). Crossref
  3. A. P. Shpak, R. I. Bihun, Z. V. Stasyuk, and Yu. A. Kunytskyi, Nanosistemi, Nanomateriali, Nanotehnologii, 8, No. 2: 339 (2010) (in Ukranian).
  4. R. I. Bihun, Z. V. Stasyuk, O. V. Strohanov, V. M. Havryliukh, and D. S. Leonov, Nanosistemi, Nanomateriali, Nanotehnologii, 13, No. 3: 459 (2015) (in Ukrainian).
  5. R. I. Bihun, M. D. Buchkovska, V. M. Havryliukh, Z. V. Stasyuk, and D. S. Leonov, Nanosistemi, Nanomateriali, Nanotehnologii, 14, No. 2: 285 (2016) (in Ukrainian).
  6. Z. V. Stasyuk, R. I. Bihun, A. V. Borodchuk, and Ya. A. Pastyrskyi, Nanosistemi, Nanomateriali, Nanotehnologii, 7, No. 2: 529 (2009) (in Ukrainian).
  7. C. R. Grovenor, H. T. Hentzell, and D. A. Smith, Acta Metall., 32, Iss. 5: 773 (1984). Crossref
  8. D. P. Singh, P. Goel, and J. P. Singh, J. Appl. Phys., 112: 104324 (2012). Crossref
  9. Fizika Tverdogo Tela: Entsiklopedicheskiy Slovar (Ed. V. G. Baryahtar) (Kiev: Naukova Dumka: 1996), vol. 1 (in Russian).
  10. Fizika Tverdogo Tela: Entsiklopedicheskiy Slovar (Ed. V. G. Baryahtar) (Kiev: Naukova Dumka: 1998), Vol. 2 (in Russian).
  11. R. I. Bihun, Z. V. Stasiuk, O. V. Strohanov, M. D. Buchkovska, and D. S. Leonov, Metallofiz. Noveishie Tehnol., 40, No. 5: 601 (2018) (in Ukrainian). Crossref
  12. K. L. Ekinci and J. M. Valles, Acta Metall., 46, Iss. 13: 4549 (1998). Crossref
  13. K. L. Ekinci and J. M. Valles, Phys. Rev. B., 58, No. 11: 7347 (1998). Crossref
  14. K. Fuchs, Math. Proc. Cambridge Phil. Soc., 34, Iss. 1: 100 (1938). Crossref
  15. E. H. Sondheimer, Adv. Phys., 1: 1 (1952). Crossref
  16. A. F. Mayadas and M. Shatzkes, Phys. Rev. B: Solid State B, 1: 1382 (1970). Crossref
  17. C. R. Pichard, C. R. Tellier, and A. J. Tosser, Thin Solid Films, 62, No. 2: 189 (1979). Crossref
  18. Y. Namba, Jap. J. Appl. Phys., 9, No. 11: 1326 (1970). Crossref
  19. P. Wißmann and H.-U. Finzel, Springer Tracts in Modern Physics (Eds. G. Höhler and Karlsruhe), vol. 223 (2007).
  20. Z. V. Stasyuk, J. Phys. Studies, 3, No. 1: 102 (1999). Crossref
  21. Z. V. Stasyuk and A. I. Lopatyns'kyy, Fizyka i Khimiya Tverdoho Tila, 2, No. 4: 521 (2001) (in Ukrainian).
  22. R. I. Bihun, Z. V. Stasyuk, and O. A. Balitskii, Physica B, 487: 73 (2016). Crossref
  23. R. I. Bihun, Z. V. Stasiuk, O. V. Strohanov, M. D. Buchkovska, V. M. Havryliukh, Ia. A. Pastyrskyi, and D. S. Leonov, Nanosistemi, Nanomateriali, Nanotehnologii, 15, No. 1: 15 (2017) (in Ukrainian). Crossref
  24. R. I. Bihun and Z. V. Stasiuk, Metallofiz. Noveishie Tekhnol., 30, No. 6: 795 (2008) (in Ukrainian).