Influence of the Stress State on L10-FePt Phase Formation within the Fe52Pt48 Film on Al2O3 Substrate
M. Yu. Verbytska1, M. N. Shamis1, K. V. Slipchenko2, T. I. Verbytska1, Iu. M. Makogon1
1National Technical University of Ukraine ‘KPI’, 37 Peremohy Ave., 03056 Kyiv, Ukraine
2V. Bakul Institute for Superhard Materials NAS of Ukraine, 2 Avtozavods’ka Str., 04074 Kyiv, Ukraine
Received: 27.07.2016. Download: PDF
The effect of stress state on the thermally activated processes of L10-FePt-ordered phase formation at annealing as well as the magnetic properties of Fe52Pt48(15 nm) film are studied by the physical materials science methods. The film is fabricated by magnetron sputtering technique on monocrystalline Al2O3 (10ˉ10) sapphire substrate. Rapid thermal annealing in nitrogen atmosphere carried out with heat rate of 400°C/s in temperature range of 500–800°C for 30 s. As determined, the disordered A1-FePt phase is formed in as-deposited film, and tensile residual mechanical stresses are presented. At the heating up to 500°C, the sign of stresses is changed, and the last ones become compressive. The A1-FePt → L10-FePt phase transformation starting at annealing temperature of 600°C is accompanied with both the lattice cell volume decreasing and the stress relaxation, and induces the change of magnetic properties. Further annealing temperature growth up to 800°C leads to increasing of both the amount of hard magnetic L10-FePt-ordered phase and the coercivity in applied magnetic field up to 14 kOe, which is perpendicular to film surface. Meanwhile, isotropy of magnetocrystalline energy is maintained.
Key words: nanosize film, L10-FePt-ordered phase, stress state, coercivity, annealing.
URL: http://mfint.imp.kiev.ua/en/abstract/v39/i01/0105.html
DOI: https://doi.org/10.15407/mfint.39.01.0105
PACS: 61.72.Hh, 68.35.Ct, 68.37.-d, 68.55.-a, 75.50.Ss, 75.50.Vv, 75.70.Ak, 81.40.Ef
Citation: M. Yu. Verbytska, M. N. Shamis, K. V. Slipchenko, T. I. Verbytska, and Iu. M. Makogon, Influence of the Stress State on L10-FePt Phase Formation within the Fe52Pt48 Film on Al2O3 Substrate, Metallofiz. Noveishie Tekhnol., 39, No. 1: 105—115 (2017) (in Ukrainian)