Influence of the Stress State on $L1_{0}$-FePt Phase Formation within the Fe$_{52}$Pt$_{48}$ Film on Al$_{2}$O$_{3}$ Substrate
M. Yu. Verbytska$^{1}$, M. N. Shamis$^{1}$, K. V. Slipchenko$^{2}$, T. I. Verbytska$^{1}$, Iu. M. Makogon$^{1}$
$^{1}$National Technical University of Ukraine ‘KPI’, 37 Peremohy Ave., 03056 Kyiv, Ukraine
$^{2}$V. Bakul Institute for Superhard Materials NAS of Ukraine, 2 Avtozavods’ka Str., 04074 Kyiv, Ukraine
Received: 27.07.2016. Download: PDF
The effect of stress state on the thermally activated processes of $L1_{0}$-FePt-ordered phase formation at annealing as well as the magnetic properties of Fe$_{52}$Pt$_{48}$(15 nm) film are studied by the physical materials science methods. The film is fabricated by magnetron sputtering technique on monocrystalline Al$_{2}$O$_{3}$ ($10\bar{1}0$) sapphire substrate. Rapid thermal annealing in nitrogen atmosphere carried out with heat rate of 400°C/s in temperature range of 500–800°C for 30 s. As determined, the disordered $A1$-FePt phase is formed in as-deposited film, and tensile residual mechanical stresses are presented. At the heating up to 500°C, the sign of stresses is changed, and the last ones become compressive. The $A1$-FePt $\rightarrow$ $L1_{0}$-FePt phase transformation starting at annealing temperature of 600°C is accompanied with both the lattice cell volume decreasing and the stress relaxation, and induces the change of magnetic properties. Further annealing temperature growth up to 800°C leads to increasing of both the amount of hard magnetic $L1_{0}$-FePt-ordered phase and the coercivity in applied magnetic field up to 14 kOe, which is perpendicular to film surface. Meanwhile, isotropy of magnetocrystalline energy is maintained.
Key words: nanosize film, $L1_{0}$-FePt-ordered phase, stress state, coercivity, annealing.
URL: http://mfint.imp.kiev.ua/en/abstract/v39/i01/0105.html
DOI: https://doi.org/10.15407/mfint.39.01.0105
PACS: 61.72.Hh, 68.35.Ct, 68.37.-d, 68.55.-a, 75.50.Ss, 75.50.Vv, 75.70.Ak, 81.40.Ef
Citation: M. Yu. Verbytska, M. N. Shamis, K. V. Slipchenko, T. I. Verbytska, and Iu. M. Makogon, Influence of the Stress State on $L1_{0}$-FePt Phase Formation within the Fe$_{52}$Pt$_{48}$ Film on Al$_{2}$O$_{3}$ Substrate, Metallofiz. Noveishie Tekhnol., 39, No. 1: 105—115 (2017) (in Ukrainian)